Zang, H., Surman, A. , Long, D. L. , Cronin, L. and Miras, H. N. (2016) Exploiting the equilibrium dynamics in the self-assembly of inorganic macrocycles based upon polyoxothiometalate building blocks. Chemical Communications, 52(58), pp. 9109-9112. (doi: 10.1039/C6CC01041E) (PMID:26982102)
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Abstract
We report the preparation and characterization of two new polyoxothiometalate species, {Mo16} = {(Mo2O2S2)8(OH)16(C4O4)2}4− (compound 1) and {Mo12} = {(Mo2O2S2)6(OH)12(CH3COO)2}2− (compound 2). Control of synthesis is achieved by the addition of the organic-template and further re-arrangement is controlled simply by the addition of potassium to a precursor compound yielding compound 2. The structures of the compounds are discussed and we also show that ion-mobility mass spectrometry can be used to resolve the species and their building blocks in solution.
| Item Type: | Articles |
|---|---|
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Moiras, Dr Haralampos and Long, Dr Deliang and Cronin, Professor Lee and Surman, Dr Andrew |
| Authors: | Zang, H., Surman, A., Long, D. L., Cronin, L., and Miras, H. N. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Chemical Communications |
| Journal Abbr.: | Chem. Commun. |
| Publisher: | Royal Society of Chemistry |
| ISSN: | 1359-7345 |
| ISSN (Online): | 1364-548X |
| Published Online: | 16 March 2016 |
| Copyright Holders: | Copyright © 2016 Royal Society of Chemistry |
| First Published: | First published in Chemical Communications 2016 |
| Publisher Policy: | Reproduced under a Creative Commons License |
| Data DOI: | 10.1039/c6cc01041e |
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