Xuan, W., Pow, R., Zheng, Q., Watfa, N., Long, D.-L. and Cronin, L. (2019) Ligand-directed template assembly for the construction of gigantic molybdenum blue wheels. Angewandte Chemie (International Edition), 58(32), pp. 10867-10872. (doi: 10.1002/anie.201901818) (PMID:31155800) (PMCID:PMC6771582)

Zheng, Q., Kupper, M., Xuan, W., Oki, H., Tsunashima, R., Long, D.-L. and Cronin, L. (2019) Anisotropic polyoxometalate cages assembled via layers of heteroanion templates. Journal of the American Chemical Society, 141(34), pp. 13479-13486. (doi: 10.1021/jacs.9b04533) (PMID:31295408) (PMCID:PMC6716119)

Martín, S., Takashima, Y., Lin, C.-G., Song, Y.-F., Miras, H. N. and Cronin, L. (2019) Integrated synthesis of gold nanoparticles coated with polyoxometalate clusters. Inorganic Chemistry, 58(7), pp. 4110-4116. (doi: 10.1021/acs.inorgchem.8b03013) (PMID:30869513)

Suárez-Marina, I., Abul-Haija, Y. M. , Turk-MacLeod, R., Gromski, P. S., Cooper, G. J.T. , Olivé Olivé, A., Colón-Santos, S. and Cronin, L. (2019) Integrated synthesis of nucleotide and nucleosides influenced by amino acids. Communications Chemistry, 2, 28. (doi: 10.1038/s42004-019-0130-7)

Gromski, P. S., Henson, A. B. , Granda, J. M. and Cronin, L. (2019) How to explore chemical space using algorithms and automation. Nature Reviews Chemistry, 3(2), pp. 119-128. (doi: 10.1038/s41570-018-0066-y)

Xuan, W., Pow, R., Watfa, N., Zheng, Q., Surman, A. J. , Long, D.-L. and Cronin, L. (2019) Stereoselective assembly of gigantic chiral molybdenum blue wheels using lanthanide ions and amino acids. Journal of the American Chemical Society, 141(3), pp. 1242-1250. (doi: 10.1021/jacs.8b09750) (PMID:30495944) (PMCID:PMC6351008)

Caramelli, D., Henson, A. , Aragon Camarasa, G. , Sharabi, S., Keenan, G. and Cronin, L. (2018) Networking chemical robots for reaction multitasking. Nature Communications, 9, 3406. (doi: 10.1038/s41467-018-05828-8) (PMID:30143646) (PMCID:PMC6109044)

Henson, A. B. , Gromski, P. S. and Cronin, L. (2018) Designing algorithms to aid discovery by chemical robots. ACS Central Science, 4(7), pp. 793-804. (doi: 10.1021/acscentsci.8b00176) (PMID:30062108) (PMCID:PMC6062836)

Granda, J. M., Donina, L., Dragone, V., Long, D.-L. and Cronin, L. (2018) Controlling an organic synthesis robot with machine learning to search for new reactivity. Nature, 559(7714), pp. 377-381. (doi: 10.1038/s41586-018-0307-8) (PMID:30022133) (PMCID:PMC6223543)

Miras, H. N. , Sartzi, H., Long, D.-L. , Sproules, S. and Cronin, L. (2018) Directed self-assembly, symmetry breaking, and electronic modulation of metal oxide clusters by pyramidal heteroanions. Chemistry: A European Journal, 24(17), pp. 4399-4411. (doi: 10.1002/chem.201705711) (PMID:29315925)

Yoshida, M. , Hinkley, T., Tsuda, S., Abul-Haija, Y. , Mcburney, R. T., Kulikov, V., Mathieson, J., Galinanes Reyes, S., Castro Spencer, M. D. and Cronin, L. (2018) Using evolutionary algorithms and machine learning to explore sequence space for the discovery of antimicrobial peptides. Chem, 4(3), pp. 533-543. (doi: 10.1016/j.chempr.2018.01.005)

Chen, J.-J., Ye, J.-C., Zhang, X.-G., Symes, M. D. , Fan, S.-C., Long, D.-L. , Zheng, M.-S., Wu, D.-Y., Cronin, L. and Dong, Q.-F. (2018) Design and performance of rechargeable sodium ion batteries, and symmetrical li-ion batteries with supercapacitor-like power density based upon polyoxovanadates. Advanced Energy Materials, 8(6), 1701021. (doi: 10.1002/aenm.201701021)

Kirkaldy, N. , Chisholm, G. , Chen, J.-J. and Cronin, L. (2018) A practical, organic-mediated, hybrid electrolyser that decouples hydrogen production at high current densities. Chemical Science, 9(6), pp. 1621-1626. (doi: 10.1039/C7SC05388F) (PMID:29675207) (PMCID:PMC5887965)

Points, L. J., Taylor, J. W., Grizou, J. , Donkers, K. and Cronin, L. (2018) Artificial intelligence exploration of unstable protocells leads to predictable properties and discovery of collective behavior. Proceedings of the National Academy of Sciences of the United States of America, 115(5), pp. 885-890. (doi: 10.1073/pnas.1711089115) (PMID:29339510) (PMCID:PMC5798325)

Parrilla Gutierrez, J. M. , Tsuda, S., Grizou, J. , Taylor, J., Henson, A. and Cronin, L. (2017) Adaptive artificial evolution of droplet protocells in a 3D-printed fluidic chemorobotic platform with configurable environments. Nature Communications, 8, 1144. (doi: 10.1038/s41467-017-01161-8) (PMID:29074987) (PMCID:PMC5658334)

Symes, M. , Cogdell, R. , Macdonald, L., McGlynn, J., Irvine, N., Alshibane, I., Bloor, L., Rausch, B., Hargreaves, J. S.J. and Cronin, L. (2017) Using earth abundant materials for the catalytic evolution of hydrogen from electron-coupled proton buffers. Sustainable Energy and Fuels, 1(8), pp. 1782-1787. (doi: 10.1039/C7SE00334J)

Vilà-Nadal, L. and Cronin, L. (2017) Design and synthesis of polyoxometalate-framework materials from cluster precursors. Nature Reviews Materials, 2, 17054. (doi: 10.1038/natrevmats.2017.54)

Duros, V., Grizou, J. , Xuan, W., Hosni, Z., Long, D.-L. , Miras, H. N. and Cronin, L. (2017) Human versus robots in the discovery and crystallization of gigantic polyoxometalates. Angewandte Chemie (International Edition), 56(36), pp. 10815-10820. (doi: 10.1002/anie.201705721) (PMID:28649740) (PMCID:PMC5577512)

Taylor, J.W., Eghtesadi, S.A., Points, L.J., Liu, T. and Cronin, L. (2017) Autonomous model protocell division driven by molecular replication. Nature Communications, 8, 237. (doi: 10.1038/s41467-017-00177-4) (PMID:28798300) (PMCID:PMC5552811)

Xuan, W., Pow, R., Long, D.-L. and Cronin, L. (2017) Exploring the molecular growth of two gigantic half-closed polyoxometalate clusters {Mo180} and {Mo130Ce6}. Angewandte Chemie (International Edition), 56(33), pp. 9727-9731. (doi: 10.1002/ange.201702957) (PMID:28508585) (PMCID:PMC5600119)

Zang, H.-Y., Purcell, J. W., Long, D.-L. , Miras, H. N. and Cronin, L. (2017) Exploring structural complexity in the discovery and self-assembly of a family of nanoscale chalcoxides from {Se8Mo36} to {Se26Mo68}. Chemical Communications, 53(61), pp. 8585-8587. (doi: 10.1039/c7cc04398h) (PMID:28718479)

Purcell, J. W., Miras, H. , Long, D.-L. , Markopoulou, P. and Cronin, L. (2017) Tellurite-squarate driven assembly of a new family of nanoscale clusters based on (Mo2O2S2)2+. Chemistry: A European Journal, 23(40), pp. 9683-9689. (doi: 10.1002/chem.201701920) (PMID:28548217) (PMCID:PMC5575479)

Zhan, C., Busche, C. , Long, D.-L. , Molina, P. I., Winter, R. S. and Cronin, L. (2017) Encapsulation of a {Cu16} cluster containing four [Cu4O4] cubanes within an isopolyoxometalate {W44} cluster. Chemical Communications, 53(52), pp. 7076-7079. (doi: 10.1039/c7cc03544f) (PMID:28627534)

Cooper, G. J.T. , Surman, A. J. , McIver, J. , Colón-Santos, S. M., Gromski, P. S., Buchwald, S., Suárez Marina, I. and Cronin, L. (2017) Miller–Urey spark-discharge experiments in the deuterium world. Angewandte Chemie (International Edition), 56(28), pp. 8079-8082. (doi: 10.1002/anie.201610837) (PMID:28474773) (PMCID:PMC5499724)

Dragone, V., Sans, V., Henson, A. B. , Granda, J. M. and Cronin, L. (2017) An autonomous organic reaction search engine for chemical reactivity. Nature Communications, 8, 15733. (doi: 10.1038/ncomms15733) (PMID:28598440) (PMCID:PMC5472751)

Yoshida, M. , Galiñanes Reyes, S. G., Tsuda, S., Horinouchi, T., Furusawa, C. and Cronin, L. (2017) Time-programmable drug dosing allows the manipulation, suppression and reversal of antibiotic drug resistance in vitro. Nature Communications, 8, 15589. (doi: 10.1038/ncomms15589) (PMID:28593940) (PMCID:PMC5472167)

Ruiz de la Oliva, A., Sans, V., Miras, H. , Long, D. L. and Cronin, L. (2017) Coding the assembly of polyoxotungstates with a programmable reaction system. Inorganic Chemistry, 56(9), pp. 5089-5095. (doi: 10.1021/acs.inorgchem.7b00206) (PMID:28414229) (PMCID:PMC5423703)

Boyd, T., Mitchell, S. G., Gabb, D., Long, D.-L. , Song, Y.-F. and Cronin, L. (2017) POMzites: a family of zeolitic polyoxometalate frameworks from a minimal building block library. Journal of the American Chemical Society, 139(16), pp. 5930-5938. (doi: 10.1021/jacs.7b01807) (PMID:28368582) (PMCID:PMC5423706)

Zhan, C. et al. (2017) A metamorphic inorganic framework that can be switched between eight single-crystalline states. Nature Communications, 8, 14185. (doi: 10.1038/ncomms14185) (PMID:28194009) (PMCID:PMC5316803)

Kulikov, V., Johnson, N. A.B., Surman, A. J. , Hutin, M., Kelly, S. K. , Hezwani, M., Long, D.-L. , Meyer, G. and Cronin, L. (2017) Spontaneous assembly of an organic-inorganic nucleic acid Z-DNA double-helix structure. Angewandte Chemie (International Edition), 56(4), pp. 1141-1145. (doi: 10.1002/anie.201606658) (PMID:27900812) (PMCID:PMC6057607)

Kitson, P. J., Glatzel, S. and Cronin, L. (2016) The digital code driven autonomous synthesis of ibuprofen automated in a 3D-printer-based robot. Beilstein Journal of Organic Chemistry, 12, pp. 2776-2783. (doi: 10.3762/bjoc.12.276) (PMID:28144350) (PMCID:PMC5238580)

Christie, L. G. , Surman, A. J. , Scullion, R. A., Xu, F., Long, D.-L. and Cronin, L. (2016) Overcoming the crystallization bottleneck: a family of gigantic inorganic {Pdx}L(x=84, 72) palladium macrocycles discovered using solution techniques. Angewandte Chemie (International Edition), 55(41), pp. 12741-12745. (doi: 10.1002/anie.201606005) (PMID:27634480) (PMCID:PMC5113701)

Xuan, W., Surman, A. J. , Zheng, Q., Long, D.-L. and Cronin, L. (2016) Self-templating and in situ assembly of a cubic cluster-of-clusters architecture based on a {Mo24Fe12} inorganic macrocycle. Angewandte Chemie (International Edition), 55(41), pp. 12703-12707. (doi: 10.1002/anie.201603298) (PMID:27358195) (PMCID:PMC5396355)

Zang, H., Surman, A. , Long, D. L. , Cronin, L. and Miras, H. N. (2016) Exploiting the equilibrium dynamics in the self-assembly of inorganic macrocycles based upon polyoxothiometalate building blocks. Chemical Communications, 52(58), pp. 9109-9112. (doi: 10.1039/C6CC01041E) (PMID:26982102)

Cameron, J. M., Vilà-Nadal, L. , Winter, R. S., Iijima, F., Murillo, J. C., Rodríguez-Fortea, A., Oshio, H., Poblet, J. M. and Cronin, L. (2016) Investigating the transformations of polyoxoanions using mass spectrometry and molecular dynamics. Journal of the American Chemical Society, 138(28), pp. 8765-8773. (doi: 10.1021/jacs.6b02245) (PMID:27321042)

Porwol, L., Henson, A. , Kitson, P. J., Long, D. L. and Cronin, L. (2016) On the fly multi-modal observation of ligand synthesis and complexation of Cu complexes in flow with ‘benchtop’ NMR and mass spectrometry. Inorganic Chemistry Frontiers, 3(7), pp. 919-923. (doi: 10.1039/C6QI00079G)

Takashima, Y., Miras, H. N. , Glatzel, S. and Cronin, L. (2016) Shrink wrapping redox-active crystals of polyoxometalate open frameworks with organic polymers via crystal induced polymerisation. Chemical Communications, 52(50), pp. 7794-7797. (doi: 10.1039/C6CC03031A) (PMID:27203804) (PMCID:PMC6055993)

Zang, H.-Y., Chen, J.-J., Long, D. L. , Cronin, L. and Miras, H. N. (2016) Assembly of inorganic [Mo2S2O2]2+ panels connected by selenite anions to nanoscale chalcogenide–polyoxometalate clusters. Chemical Science, 7(6), pp. 3798-3804. (doi: 10.1039/c5sc04944j)

Kitson, P. J., Glatzel, S., Chen, W., Lin, C.-G., Song, Y.-F. and Cronin, L. (2016) 3D printing of versatile reactionware for chemical synthesis. Nature Protocols, 11(5), pp. 920-936. (doi: 10.1038/nprot.2016.041) (PMID:27077333)

Sans Sangorrin, V. and Cronin, L. (2016) Towards dial-a-molecule by integrating continuous flow, analytics and self-optimisation. Chemical Society Reviews, 45(8), pp. 2032-2043. (doi: 10.1039/C5CS00793C) (PMID:26815081) (PMCID:PMC6057606)

Points, L. J., Cooper, G. J.T. , Dolbecq, A., Mialane, P. and Cronin, L. (2016) An all-inorganic polyoxometalate–polyoxocation chemical garden. Chemical Communications, 52(9), pp. 1911-1914. (doi: 10.1039/c5cc09536k) (PMID:26681204)

Martin-Sabi, M., Winter, R. S., Lydon, C., Cameron, J. M., Long, D.-L. and Cronin, L. (2016) Rearrangement of {α-P2W15} to {PW6} moieties during the assembly of transition-metal-linked polyoxometalate clusters. Chemical Communications, 52(5), pp. 919-921. (doi: 10.1039/C5CC08486E) (PMID:26581307)

Bloor, L. G., Solarska, R., Bienkowski, K., Kulesza, P. J., Augustynski, J., Symes, M. D. and Cronin, L. (2016) Solar-driven water oxidation and decoupled hydrogen production mediated by an electron-coupled-proton buffer. Journal of the American Chemical Society, 138(21), pp. 6707-6710. (doi: 10.1021/jacs.6b03187) (PMID:27159121) (PMCID:PMC5033397)

Surman, A. J. , Robbins, P. J., Ujma, J., Zheng, Q., Barran, P. E. and Cronin, L. (2016) Sizing and discovery of nanosized polyoxometalate clusters by mass spectrometry. Journal of the American Chemical Society, 138(11), pp. 3824-3830. (doi: 10.1021/jacs.6b00070) (PMID:26906879) (PMCID:PMC5033399)

Glatzel, S., Hezwani, M., Kitson, P. J., Gromski, P. S., Schürer, S. and Cronin, L. (2016) A portable 3D printer system for the diagnosis and treatment of multidrug-resistant bacteria. Chem, 1(3), pp. 494-504. (doi: 10.1016/j.chempr.2016.08.008)

Sartzi, H., Miras, H. N. , Vila-Nadal, L. , Long, D. L. and Cronin, L. (2015) Trapping the δ isomer of the polyoxometalate-based Keggin cluster with a tripodal ligand. Angewandte Chemie (International Edition), 54(51), pp. 15488-15492. (doi: 10.1002/anie.201505377) (PMID:26511859)

Zhan, C.-H., Winter, R. S., Zheng, Q., Yan, J., Cameron, J. M., Long, D.-L. and Cronin, L. (2015) Assembly of tungsten-oxide-based pentagonal motifs in solution leads to nanoscale {W48}, {W56}, and {W92} polyoxometalate clusters. Angewandte Chemie (International Edition), 54(48), pp. 14308-14312. (doi: 10.1002/anie.201506170) (PMID:26449850)

Tsuda, S., Jaffery, H., Doran, D., Hezwani, M., Robbins, P. J., Yoshida, M. and Cronin, L. (2015) Customizable 3D printed 'Plug and Play' millifluidic devices for programmable fluidics. PLoS ONE, 10(11), e0141640. (doi: 10.1371/journal.pone.0141640) (PMID:26558389) (PMCID:PMC4641590)

Henson, A. , Parrilla Gutierrez, J. M. , Hinkley, T., Tsuda, S. and Cronin, L. (2015) Towards heterotic computing with droplets in a fully automated droplet-maker platform. Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, 373(2046), 20140221. (doi: 10.1098/rsta.2014.0221) (PMID:26078348)

Zheng, Q., Vila-Nadal, L. , Busche, C. , Mathieson, J. S., Long, D.-L. and Cronin, L. (2015) Following the reaction of heteroanions inside a {W18O56} polyoxometalate nanocage by NMR spectroscopy and mass spectrometry. Angewandte Chemie (International Edition), 127(27), pp. 8006-8010. (doi: 10.1002/ange.201502295)

Zhang, B., Pradeep, C. P., Cronin, L. and Liu, T. (2015) Self-assembly of triangular polyoxometalate–organic hybrid macroions in mixed solvents. Chemical Communications, 51(41), pp. 8630-8633. (doi: 10.1039/C5CC02003D) (PMID:25900154)

MacDonell, A., JOHNSON, N. A.B., Surman, A. J. and Cronin, L. (2015) Configurable nanosized metal oxide oligomers via precise “click” coupling control of hybrid polyoxometalates. Journal of the American Chemical Society, 137(17), pp. 5662-5665. (doi: 10.1021/jacs.5b02466) (PMID:25846763)

Sans Sangorrin, V., Porwol, L., Dragone, V. and Cronin, L. (2015) A self optimizing synthetic organic reactor system using real-time in-line NMR spectroscopy. Chemical Science, 6(2), pp. 1258-1264. (doi: 10.1039/C4SC03075C)

Lee, M. P., Cooper, G. J.T. , Hinkley, T., Gibson, G. M. , Padgett, M. J. and Cronin, L. (2015) Development of a 3D printer using scanning projection stereolithography. Scientific Reports, 5, 9875. (doi: 10.1038/srep09875) (PMID:25906401) (PMCID:PMC4407727)

Winter, R. S., Long, D.-L. and Cronin, L. (2015) Synthesis and characterization of a series of [M2(β-SiW8O31)2]n− clusters and mechanistic insight into the reorganization of {β-SiW8O31} into {α-SiW9O34}. Inorganic Chemistry, 54(8), pp. 4151-4155. (doi: 10.1021/acs.inorgchem.5b00405)

Rodriguez-Garcia, M., Surman, A. J. , Cooper, G. J.T. , Suarez Marina, I., Hosni, Z., Lee, M. P. and Cronin, L. (2015) Formation of oligopeptides in high yield under simple programmable conditions. Nature Communications, 6, 8385. (doi: 10.1038/ncomms9385) (PMID:26442968) (PMCID:PMC4633627)

Parrilla Gutierrez, J. M. , Hinkley, T., Taylor, J. W. and Cronin, L. (2014) Evolution of oil droplets in a chemorobotic platform. Nature Communications, 5, 5571. (doi: 10.1038/ncomms6571) (PMID:25482304) (PMCID:PMC4268700)

Busche, C. et al. (2014) Design and fabrication of memory devices based on nanoscale polyoxometalate clusters. Nature, 515(7528), pp. 545-549. (doi: 10.1038/nature13951) (PMID:25409147)

Lin, C.-G., Chen, W., Long, D. L. , Cronin, L. and Song, Y.-F. (2014) Step-by-step covalent modification of Cr-templated Anderson-type polyoxometalates. Dalton Transactions, 43(23), pp. 8587-8590. (doi: 10.1039/c4dt00033a) (PMID:24695647)

Molina, P. I., Miras, H. N. , Long, D.-L. and Cronin, L. (2014) Assembly and core transformation properties of two tetrahedral clusters:([FeIII13P8W60O227(OH)15(H2O)2]30− and [FeIII13P8W60O224(OH)12(PO4)4]33−. Dalton Transactions, 43(13), pp. 5190-5199. (doi: 10.1039/c3dt53382d)

Cameron, J. M., Gao, J., Vila-Nadal, L. , Long, D.-L. and Cronin, L. (2014) Formation, self-assembly and transformation of a transient selenotungstate building block into clusters, chains and macrocycles. Chemical Communications, 50(17), pp. 2155-2157. (doi: 10.1039/C3CC49293A)

Cameron, J. M., Gao, J., Long, D. L. and Cronin, L. (2014) Self-assembly and structural transformations of high-nuclearity palladium-rich polyoxometalates. Inorganic Chemistry Frontiers, 1(2), pp. 178-185. (doi: 10.1039/c3qi00075c)

Sans, V., Glatzel, S., Douglas, F. J., MacLaren, D. A. , Lapkin, A. and Cronin, L. (2014) Non-equilibrium dynamic control of gold nanoparticle and hyper-branched nanogold assemblies. Chemical Science, 5(3), pp. 1153-1157. (doi: 10.1039/C3SC53223B)

Zang, H.-Y., Ruiz de la Oliva, A., Miras, H. N. , Long, D.-L. , McBurney, R. T. and Cronin, L. (2014) Discovery of gigantic molecular nanostructures using a flow reaction array as a search engine. Nature Communications, 5, pp. 1-8. (doi: 10.1038/ncomms4715)

Chisholm, G. , Kitson, P. J., Kirkaldy, N. D., Bloor, L. G. and Cronin, L. (2014) 3D printed flow plates for the electrolysis of water: an economic and adaptable approach to device manufacture. Energy and Environmental Science, 7(9), pp. 3026-3032. (doi: 10.1039/C4EE01426J)