Long, D.L. , Yan, J., Ruiz De La Oliva, A., Busche, C. , Miras, H.N. , Errington, R.J. and Cronin, L. (2013) A redox-triggered structural rearrangement in an iodate-templated polyoxotungstate cluster cage. Chemical Communications, 49(84), pp. 9731-9733. (doi: 10.1039/c3cc45659e)
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Abstract
The new tungstatoiodate, α-[H5W18O59(IO3)]6−, containing IVO3− within a {W18O54} metal oxide framework has been prepared and shown by X-ray crystallography and mass spectrometry to be derived from the fully oxidised [H3W18O56(IO6)]6− by two-electron reduction accompanied by a redox-triggered structural rearrangement where three I–O covalent bonds are broken.
Item Type: | Articles |
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Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Busche, Dr Christopher and Yan, Mr Jun and Moiras, Professor Haralampos and Long, Dr Deliang and Cronin, Professor Lee |
Authors: | Long, D.L., Yan, J., Ruiz De La Oliva, A., Busche, C., Miras, H.N., Errington, R.J., and Cronin, L. |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | Chemical Communications |
Journal Abbr.: | Chem. Comm. |
Publisher: | Royal Society of Chemistry |
ISSN: | 1359-7345 |
ISSN (Online): | 1364-548X |
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