Exploring time assembly of supramolecular polyoxometalate triangular morphologies with johnson solid cores: [(MnII(H2O)3)2(K⊂{α-GeW10MnII 2O38}3)]19−

Molina, P. I., Miras, H. N. , Long, D.-L. and Cronin, L. (2013) Exploring time assembly of supramolecular polyoxometalate triangular morphologies with johnson solid cores: [(MnII(H2O)3)2(K⊂{α-GeW10MnII 2O38}3)]19−. Inorganic Chemistry, 52(16), pp. 9284-9289. (doi: 10.1021/ic400542x)

Abstract

A new polyoxometalate (POM) cluster compound is presented which incorporates a trimeric assembly of Keggin-type germanotungstate fragments trapping a Johnsontype solid {Mn8} core. The mixed K−Li salt of the polyanion [(MnII(H2O)3)2(K⊂{α-GeW10MnII 2O38}3)]19− was characterized in the solid state and solution. The correlation of the assembly processes and the observed architecture of the “trinity” family of POMs is discussed.

• Item Type: Articles
• Status: Published
• Refereed: Yes
• Glasgow Author(s) Enlighten ID: Molina-Sanchez, Mr Pedro and Moiras, Professor Haralampos and Long, Dr Deliang and Cronin, Professor Lee
• Authors: Molina, P. I., Miras, H. N., Long, D.-L., and Cronin, L.
• Subjects: Q Science > QD Chemistry
• College/School: College of Science and Engineering > School of Chemistry
• Journal Name: Inorganic Chemistry
• Publisher: American Chemical Society
• ISSN: 0020-1669
• ISSN (Online): 1520-510X