Vilà-Nadal, L. , Peuntinger, K., Busche, C. , Yan, J., Lüders, D., Long, D. , Poblet, J.M., Guldi, D.M. and Cronin, L. (2013) Polyoxometalate {W18O56XO6} clusters with embedded redox-active main-group templates as localized inner-cluster radicals. Angewandte Chemie (International Edition), 52(37), pp. 9695-9699. (doi: 10.1002/anie.201303126)
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Abstract
Non-mixed-valent reduced polyoxometalates, namely {W18O56XO6} Dawson-like clusters (X=IVII or TeVI) with a localized redox active template have been synthesized and redox properties compared with the pure tungsten control (that is, X=WVI). Upon one-electron reduction, the electron localizes on the main-group element, giving IVI or TeV, respectively. These clusters have potential as a new type of electron-transfer reagent.
| Item Type: | Articles |
|---|---|
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Yan, Mr Jun and Busche, Dr Christopher and Vila-Nadal, Dr Laia and Long, Dr Deliang and Cronin, Professor Lee |
| Authors: | Vilà-Nadal, L., Peuntinger, K., Busche, C., Yan, J., Lüders, D., Long, D., Poblet, J.M., Guldi, D.M., and Cronin, L. |
| Subjects: | Q Science > QD Chemistry |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Angewandte Chemie (International Edition) |
| Journal Abbr.: | Angew Chem Int Ed Engl |
| Publisher: | Wiley |
| ISSN: | 1433-7851 |
| ISSN (Online): | 1521-3773 |
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