Manos, M.J., Miras, H.N. , Tangoulis, V., Woollins, J.D., Slawin, A.M.Z. and Kabanos, T.A. (2003) Polyoxovanadium(IV) sulfite compounds: Synthesis, structural, and physical studies. Angewandte Chemie (International Edition), 42(4), pp. 425-427. (doi: 10.1002/anie.200390129)
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Abstract
An unexplored family of polyoxometalates has evolved through the synthesis and structural characterization of vanadium(IV) sulfite heteropolyanions. The hexanuclear vanadium(IV) compound, which is ferromagnetic down to 2 K, exhibits a unique structural motif for such metal species, with a central cubic {M<sub>4</sub>O<sub>2</sub>(OH)<sub>2</sub>} fragment and metal centers at two of the corners of the cluster.
Item Type: | Articles |
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Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Moiras, Professor Haralampos |
Authors: | Manos, M.J., Miras, H.N., Tangoulis, V., Woollins, J.D., Slawin, A.M.Z., and Kabanos, T.A. |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | Angewandte Chemie (International Edition) |
Journal Abbr.: | Angew. Chem. Int. Ed. Engl. |
Publisher: | Wiley - V C H Verlag GmbH & Co. KGaA |
ISSN: | 1433-7851 |
ISSN (Online): | 1521-3773 |
Published Online: | 28 January 2003 |
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