Polyoxovanadium(IV) sulfite compounds: Synthesis, structural, and physical studies

Manos, M.J., Miras, H.N. , Tangoulis, V., Woollins, J.D., Slawin, A.M.Z. and Kabanos, T.A. (2003) Polyoxovanadium(IV) sulfite compounds: Synthesis, structural, and physical studies. Angewandte Chemie (International Edition), 42(4), pp. 425-427. (doi: 10.1002/anie.200390129)

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Abstract

An unexplored family of polyoxometalates has evolved through the synthesis and structural characterization of vanadium(IV) sulfite heteropolyanions. The hexanuclear vanadium(IV) compound, which is ferromagnetic down to 2 K, exhibits a unique structural motif for such metal species, with a central cubic {M<sub>4</sub>O<sub>2</sub>(OH)<sub>2</sub>} fragment and metal centers at two of the corners of the cluster.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Moiras, Professor Haralampos
Authors: Manos, M.J., Miras, H.N., Tangoulis, V., Woollins, J.D., Slawin, A.M.Z., and Kabanos, T.A.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Angewandte Chemie (International Edition)
Journal Abbr.:Angew. Chem. Int. Ed. Engl.
Publisher:Wiley - V C H Verlag GmbH & Co. KGaA
ISSN:1433-7851
ISSN (Online):1521-3773
Published Online:28 January 2003

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