Miras, H.N. , Stone, D.J., McInnes, E.J.L., Raptis, R.G., Baran, P., Chilas, G.I., Sigalas, M.P., Kabanos, T.A. and Cronin, L. (2008) Solution identification and solid state characterisation of a heterometallic polyoxometalate {Mo(11)V(7)}: Mo(11)(VI)V(5)(V) V(2)(IV)O(52)(mu(9)-SO(3))](7-). Chemical Communications(39), pp. 4703-4705. (doi: 10.1039/B811279G)
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Abstract
A polyoxomolybdenum/vanadium-sulfite {M(18)} cluster-based compound, Mo(11)(VI)V(5)(V)V(2)(IV)O(52)(mu(9)-SO(3))](7-), is reported that exhibits a unique structural motif, arising from the incorporation of five V(V) and two V(IV) ions into a {M(18)} cluster framework templated by SO(3)(2-); this cluster compostion was first identified using cryospray mass spectrometry.
Item Type: | Articles |
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Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Moiras, Professor Haralampos and Cronin, Professor Lee |
Authors: | Miras, H.N., Stone, D.J., McInnes, E.J.L., Raptis, R.G., Baran, P., Chilas, G.I., Sigalas, M.P., Kabanos, T.A., and Cronin, L. |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | Chemical Communications |
Journal Abbr.: | Chem. Comm. |
Publisher: | Royal Society of Chemistry |
ISSN: | 1359-7345 |
ISSN (Online): | 1364-548X |
Published Online: | 15 September 2008 |
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