Miras, H.N. , Zhao, H., Herchel, R., Rinaldi, C., Perez, S. and Raptis, R.G. (2008) Synthesis and characterization of linear trinuclear Pd, Co, and Pd/Co pyrazolate complexes. European Journal of Inorganic Chemistry(30), pp. 4745-4755. (doi: 10.1002/ejic.200800349)
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Abstract
A family of dinuclear and linear trinuclear Co/Pd pyrazolate compounds, namely, Bu(4)N](2)Co(2)(mu-4-Cl-3,5-Me(2)-pz)(2)Cl(4)] (1), Bu(4)N](2)Co(2)(mu-4-Br-3,5-Me(2)-pz)(2)Br(4)] (2), Bu(4)N](2)Co(2)(4-I-3,5-Me(2)-pz)(2)Cl(4)] (3), Et(4)N](2)Pd(2)Co(4-Br-3,5-Me(2)-pz)(4)Cl(4)] (4), Et(3)NH](4)PdCo(2)(4-Br-3,5-Me(2)-pz)(4)Cl(4)]NO(3)](2) (5), Et(3)NH](2)-Pd Co(2)(3-Me-5-Ph-pz)(4)Cl(4)] (6), Et(3)NH](2)Pd(3)(4-Br-3,5-Me(2)-pz)(4)Cl(4)] (7), and Co(3)(3,5-Me(2)-pz)(4)(3,5-Me(2)-pzH)(2)(CH(3)CO(2))(2)] (8) was synthesized. The single-phase nature of the solids was established by single-crystal X-ray diffraction, thermal analysis, and spectroscopic techniques. Moreover, the magnetic behavior is studied and a magnetostructural comparison to the corresponding carboxylate analogues is made.
| Item Type: | Articles |
|---|---|
| Keywords: | Heterometallic compounds, nitrogen heterocycles, magnetic properties, palladium, cobalt |
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Moiras, Professor Haralampos |
| Authors: | Miras, H.N., Zhao, H., Herchel, R., Rinaldi, C., Perez, S., and Raptis, R.G. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | European Journal of Inorganic Chemistry |
| Journal Abbr.: | Euro. J. Inorg. Chem |
| ISSN: | 1434-1948 |
| ISSN (Online): | 1099-0682 |
| Published Online: | 16 September 2008 |
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