Thiel, J. et al. (2010) Modular inorganic polyoxometalate frameworks showing emergent properties: redox alloys. Angewandte Chemie (International Edition), 49(39), pp. 6984-6988. (doi: 10.1002/anie.201002672)
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Abstract
Alloy, alloy: A pure cobalt-based Keggin network linked by W-O-Co interactions is “alloyed” with a pure manganese-based Keggin network, linked by W-O-Mn interactions. These isostructural alloys are solid solutions of the Co and Mn nets. The alloys are prepared by the stoichiometric mixing of the components of each discrete network, leading to a series of single-crystalline mixed transition-metal frameworks with novel redox properties.
| Item Type: | Articles |
|---|---|
| Keywords: | alloys, framework materials, polyoxometalates, redox chemistry |
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Thiel, Mr Johannes and Moiras, Professor Haralampos and Rosnes, Dr Mali and Boyd, Mr Thomas and Ritchie, Mr Christopher and Long, Dr Deliang and Cronin, Professor Lee and Streb, Mr Carsten |
| Authors: | Thiel, J., Ritchie, C., Miras, H.N., Streb, C., Mitchell, S.G., Boyd, T., Ochoa, M.N.C., Rosnes, M., McIvet, J., Long, D.L., and Cronin, L. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Angewandte Chemie (International Edition) |
| Publisher: | Wiley - V C H Verlag GmbH & Co. KGaA |
| ISSN: | 1433-7851 |
| ISSN (Online): | 1521-3757 |
| Published Online: | 14 July 2010 |
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