Modular inorganic polyoxometalate frameworks showing emergent properties: redox alloys

Thiel, J. et al. (2010) Modular inorganic polyoxometalate frameworks showing emergent properties: redox alloys. Angewandte Chemie (International Edition), 49(39), pp. 6984-6988. (doi: 10.1002/anie.201002672)

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Alloy, alloy: A pure cobalt-based Keggin network linked by W-O-Co interactions is “alloyed” with a pure manganese-based Keggin network, linked by W-O-Mn interactions. These isostructural alloys are solid solutions of the Co and Mn nets. The alloys are prepared by the stoichiometric mixing of the components of each discrete network, leading to a series of single-crystalline mixed transition-metal frameworks with novel redox properties.

Item Type:Articles
Keywords:alloys, framework materials, polyoxometalates, redox chemistry
Glasgow Author(s) Enlighten ID:Thiel, Mr Johannes and Moiras, Dr Haralampos and Rosnes, Dr Mali and Boyd, Mr Thomas and Ritchie, Mr Christopher and Long, Dr Deliang and Cronin, Professor Lee and Streb, Mr Carsten
Authors: Thiel, J., Ritchie, C., Miras, H.N., Streb, C., Mitchell, S.G., Boyd, T., Ochoa, M.N.C., Rosnes, M., McIvet, J., Long, D.L., and Cronin, L.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Angewandte Chemie (International Edition)
Publisher:Wiley - V C H Verlag GmbH & Co. KGaA
ISSN (Online):1521-3757
Published Online:14 July 2010

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