Gabb, D., Pradeep, C.P., Miras, H.N. , Mitchell, S.G., Long, D.L. and Cronin, L. (2012) Organic-soluble lacunary {M-2(P2W15)(2)} polyoxometalate sandwiches showing a previously unseen alpha beta beta alpha isomerism. Dalton Transactions, 41(33), pp. 10000-10005. (doi: 10.1039/C2DT30616F)
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Abstract
New polyoxometalate `sandwiches' have been formed where two P2W15O56](12-)lacunary Dawson clusters encapsulate two transition metal ions to give clusters with the general formula M-2(II)(P2W15O56)(2)](20-) (where M = Mn, Co, and Ni respectively), Fe-2(III)(P2W15O56)(2)](18-), and Cu-4(II)(P2W15O56)2](16-). The Mn, Co, and Ni clusters exhibit a hitherto unseen alpha beta beta alpha isomeric geometry and all five compounds are associated with tetrabutylammonium cations which allow for their dissolution in non-aqueous solvent.
| Item Type: | Articles |
|---|---|
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Moiras, Dr Haralampos and Gabb, Mr David and Long, Dr Deliang and Cronin, Professor Lee |
| Authors: | Gabb, D., Pradeep, C.P., Miras, H.N., Mitchell, S.G., Long, D.L., and Cronin, L. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Dalton Transactions |
| Publisher: | Royal Society of Chemistry |
| ISSN: | 1477-9226 |
| ISSN (Online): | 1477-9234 |
| Published Online: | 16 July 2012 |
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