Assembly of a gigantic polyoxometalate cluster {W200Co8O660} in a networked reactor system

de la Oliva, A.R., Sans Sangorrin, V., Miras, H.N. , Yan, J., Zang, H., Richmond, C.J., Long, D.L. and Cronin, L. (2012) Assembly of a gigantic polyoxometalate cluster {W200Co8O660} in a networked reactor system. Angewandte Chemie (International Edition), 51(51), pp. 12759-12762. (doi: 10.1002/anie.201206572)

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Abstract

A giant leap: A networked reactor system was used for the first time for the discovery and synthesis of new polyoxometalates, including the gigantic title system. The system comprises of three reactors connected in a triangular array with a central triply connected reactor. This system was used to screen multiple one-pot reactions and reaction variables for the automated syntheses of polyoxometalates.

Item Type:Articles
Keywords:networked reaction system, one-pot reactions, polyoxometalates, polyoxotungstates, self-assembly.
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Yan, Mr Jun and Moiras, Professor Haralampos and Richmond, Mr Craig and Long, Dr Deliang and Cronin, Professor Lee and Sans Sangorrin, Dr Victor
Authors: de la Oliva, A.R., Sans Sangorrin, V., Miras, H.N., Yan, J., Zang, H., Richmond, C.J., Long, D.L., and Cronin, L.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Angewandte Chemie (International Edition)
Journal Abbr.:Angew Chem Int Ed Engl
Publisher:Wiley - V C H Verlag GmbH & Co. KGaA
ISSN:1433-7851
ISSN (Online):1521-3773
Published Online:23 November 2012

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