Gassensmith, J.J., Smaldone, R.A., Forgan, R.S. , Wilmer, C.E., Cordes, D.B., Botros, Y.Y., Slawin, A.M.Z., Snurr, R.Q. and Stoddart, J.F. (2012) Polyporous metal-coordination frameworks. Organic Letters, 14(6), pp. 1460-1463. (doi: 10.1021/ol300199a)
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Publisher's URL: http://pubs.acs.org/doi/abs/10.1021/ol300199a
Abstract
Starting from a chiral building block—α-cyclodextrin—and rubidium salts, the crystallization of a complex of chiral helices, which constitute a “green” porous coordination polymer, has been realized. Cyclodextrin molecules coordinated by rubidium ions form porous, infinitely long left-handed helical channels, interdigitated with each other. A theoretical examination of the potential of this new material to act as a medium for chiral separation is presented.
| Item Type: | Articles |
|---|---|
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Forgan, Professor Ross |
| Authors: | Gassensmith, J.J., Smaldone, R.A., Forgan, R.S., Wilmer, C.E., Cordes, D.B., Botros, Y.Y., Slawin, A.M.Z., Snurr, R.Q., and Stoddart, J.F. |
| Subjects: | Q Science > QD Chemistry |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Organic Letters |
| ISSN: | 1523-7060 |
| ISSN (Online): | 1523-7052 |
| Published Online: | 29 February 2012 |
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