Boyd, T., Mitchell, S.G., Gabb, D., Long, D.L. and Cronin, L. (2011) Investigating cation binding in the polyoxometalate-super-crown [P8W48O184]40−. Chemistry: A European Journal, 17(43), pp. 12010-12014. (doi: 10.1002/chem.201101666)
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Abstract
An adaptable polyoxometalate macrocycle: The crown-type polyoxometalate [P8W48O184]40− has been prepared in the absence of potassium to give two new mixed lithium/ammonium compounds, allowing cation binding within the heteropolyanion to be investigated. Characterization of binding sites in the {P8W48} cluster could enable prediction of reaction products and selective functionalization of internal and external binding sites.
| Item Type: | Articles |
|---|---|
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Long, Dr Deliang and Cronin, Professor Lee |
| Authors: | Boyd, T., Mitchell, S.G., Gabb, D., Long, D.L., and Cronin, L. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Chemistry: A European Journal |
| ISSN: | 0947-6539 |
| Published Online: | 26 September 2011 |
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