Assembly of molecular "layered" heteropolyoxometalate architectures

Gao, J., Yan, J., Beeg, S., Long, D.L. and Cronin, L. (2012) Assembly of molecular "layered" heteropolyoxometalate architectures. Angewandte Chemie (International Edition), 51(14), pp. 3373-3376. (doi: 10.1002/anie.201108428)

Full text not currently available from Enlighten.


Neoclassical architecture: A new family of heteropolyoxometalates with “pagoda”-shaped building blocks [Te<sub>n</sub>W<sub>6n+3</sub>O<sub>21n+12</sub>]<sup>(6+2n)−</sup> (n=1, 2, 3) was discovered by adding {TeW<sub>6</sub>O<sub>21</sub>} layers on a classic {TeW<sub>9</sub>O<sub>33</sub>} fragment. Linking of the units allowed the generation of nanostructured clusters whose gross conformation is cation controlled. Studies of the redox behaviors of the multi-layered clusters indicate that the Te<sup>IV</sup> template is redox-active.

Item Type:Articles
Glasgow Author(s) Enlighten ID:Yan, Mr Jun and Long, Dr Deliang and Cronin, Professor Lee
Authors: Gao, J., Yan, J., Beeg, S., Long, D.L., and Cronin, L.
Subjects:Q Science > QD Chemistry
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Angewandte Chemie (International Edition)
Publisher:Wiley - V C H Verlag GmbH & Co. KGaA
Published Online:28 February 2012

University Staff: Request a correction | Enlighten Editors: Update this record