Clean and efficient synthesis of O-silylcarbamates and ureas in supercritical carbon dioxide

Fuchter, M.J., Smith, C.J., Tsang, M.W.S., Boyer, A. , Saubern, S., Ryan, J.H. and Holmes, A.B. (2008) Clean and efficient synthesis of O-silylcarbamates and ureas in supercritical carbon dioxide. Chemical Communications(18), pp. 2152-2154. (doi: 10.1039/B801537F)

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Abstract

The synthesis of a family of O-silylcarbamates from the corresponding silylamines has been achieved simply by heating the silylamine in supercritical carbon dioxide (scCO<sub>2</sub>), and these O-silylcarbamates have been shown to be effective precursors for the synthesis of a range of symmetrical and unsymmetrical ureas.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Boyer, Dr Alistair
Authors: Fuchter, M.J., Smith, C.J., Tsang, M.W.S., Boyer, A., Saubern, S., Ryan, J.H., and Holmes, A.B.
Subjects:Q Science > QD Chemistry
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Chemical Communications
Journal Abbr.:Chem. Comm.
ISSN:1359-7345
ISSN (Online):1364-548X
Published Online:02 April 2008

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