Diphenylzirconocene

Clegg, W., Horsburgh, L., Lindsay, D. and Mulvey, R.E. (1998) Diphenylzirconocene. Acta Crystallographica. Section C: Crystal Structure Communications, 54(3), pp. 315-317. (doi: 10.1107/S0108270197019343)

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Publisher's URL: http://dx.doi.org/10.1107/S0108270197019343

Abstract

The title compound [Zr(C<sub>5</sub>H<sub>5</sub>)<sub>2</sub>(C<sub>6</sub>H<sub>5</sub>)<sub>2</sub>] has two cyclopentadienyl and two phenyl ligands arranged in a distorted tetrahedral geometry around Zr. Steric interactions produce an opening of the Cp-Zr-Cp angle to 131.7 (1)° and a tilting of both phenyl rings in their own planes about the Zr-C bonds by several degrees.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Lindsay, Dr David
Authors: Clegg, W., Horsburgh, L., Lindsay, D., and Mulvey, R.E.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Acta Crystallographica. Section C: Crystal Structure Communications
Publisher:Wiley-Blackwell Publishing, Inc.
ISSN:0108-2701
ISSN (Online):1600-5759
Published Online:01 January 1998

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