Mitchell, S. G. et al. (2011) A mixed-valence manganese cubane trapped by inequivalent trilacunary polyoxometalate ligands. Angewandte Chemie (International Edition), 50(39), pp. 9154-9157. (doi: 10.1002/anie.201102727)
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Abstract
The title compound contains an embedded mixed-valence {Mn5O6} cubane core, which is structurally similar to the active site in photosystem II. Solid-, solution-, and gas-phase studies indicate the presence of three lacunary Keggin fragments, thereby giving insight into the complex solution chemistry of plenary POM fragments.
| Item Type: | Articles |
|---|---|
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Moiras, Professor Haralampos and Winter, Mr Ross and Khanra, Dr Sumit and Cogdell, Professor Richard and Long, Dr Deliang and Cooper, Dr Geoff and Cronin, Professor Lee |
| Authors: | Mitchell, S. G., Molina, P. I., Khanra, S., Miras, H. N., Prescimone, A., Cooper, G. J.T., Winter, R. W., Brechin, E. K., Long, D., Cogdell, R. J., and Cronin, L. |
| College/School: | College of Medical Veterinary and Life Sciences > School of Molecular Biosciences College of Science and Engineering > School of Chemistry |
| Journal Name: | Angewandte Chemie (International Edition) |
| Publisher: | Wiley - V C H Verlag GmbH & Co. KGaA |
| ISSN: | 1433-7851 |
| ISSN (Online): | 1521-3773 |
| Published Online: | 24 August 2011 |
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