Cook, J.A., Osborne, M.J. and Rice, D.A. (1976) Complexes of the phenylmethane nitronato and propane-2-nitronato anions with divalent metal ions. Journal of Inorganic and Nuclear Chemistry, 38(4), pp. 711-713. (doi: 10.1016/0022-1902(76)80342-9)
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Abstract
Complexes of the nitronato anions PhCHNO<sub>2</sub><sup>−</sup> and (CH<sub>3</sub>)<sub>2</sub>CNO<sub>2</sub><sup>−</sup> have been prepared with a variety of divalent metals. Compounds of four stoicheiometries have been isolated; these are MA<sub>2</sub>, 2L, MA<sub>2</sub>, B, CuA<sub>2</sub>, and HgACl (where M = Mn(II), Co(II), Fe(II) or Ni(II), A = nitronato anion, L = monodentate ligand and B = bidentate ligand). The magnetic and spectral properties are interpreted as showing all the species except HgACl to contain 6 coordinate metal atoms. On the evidence of IR spectra, it is possible to distinguish between bridging and chelating nitronato anions by examining the position of ν<sub>asym</sub> NO<sub>2</sub> and to deduce that in the species HgACl there are mercury-carbon bonds.
| Item Type: | Articles |
|---|---|
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Osborne, Professor Michael |
| Authors: | Cook, J.A., Osborne, M.J., and Rice, D.A. |
| Subjects: | Q Science > QD Chemistry |
| College/School: | College of Social Sciences > School of Education > Social Justice Place and Lifelong Education College of Social Sciences > School of Education > People, Place & Social Change |
| Journal Name: | Journal of Inorganic and Nuclear Chemistry |
| ISSN: | 0022-1902 |
| Published Online: | 16 May 2003 |
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