Braun, M.G., Vincent, A., Boumediene, M. and Prunet, J. (2011) Highly demanding cross metathesis in the synthesis of the C16-C30 fragment of dolabelide C. Journal of Organic Chemistry, 76(12), pp. 4921-4929. (doi: 10.1021/jo200466t)
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Publisher's URL: http://dx.doi.org/10.1021/jo200466t
Abstract
A highly demanding cross-metathesis (CM) reaction for the formation of the C24–C25 trisubstituted olefin of dolabelide C has been optimized. A difference in reactivity between the E and Z enone isomers in this reaction was uncovered, and the selection of the Z isomer of the starting enone was critical for the success of the cross-metathesis. Application to the synthesis of the C16–C30 fragment of dolabelide C is reported.
Item Type: | Articles |
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Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Prunet, Dr Joelle |
Authors: | Braun, M.G., Vincent, A., Boumediene, M., and Prunet, J. |
Subjects: | Q Science > QD Chemistry |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | Journal of Organic Chemistry |
Journal Abbr.: | J. Org. Chem. |
ISSN: | 0022-3263 |
ISSN (Online): | 1520-6904 |
Published Online: | 02 May 2011 |
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