Yang, X., Loos, J., Veenstra, S., Verhees, W., Wienk, M., Kroon, J., Michels, M. and Janssen, R. (2005) Nanoscale morphology of high-performance polymer solar cells. Nano Letters, 5(4), pp. 579-583. (doi: 10.1021/nl048120i)
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Abstract
Transmission electron microscopy and electron diffraction are used to study the changes in morphology of composite films of poly(3-hexylthiophene) (P3HT) and a methanofullerene derivative (PCBM) in bulk heterojunction solar cells. Thermal annealing produces and stabilizes a nanoscale interpenetrating network with crystalline order for both components. P3HT forms long, thin conducting nanowires in a rather homogeneous, nanocrystalline PCBM film. Both the improved crystalline nature of films and increased but controlled demixing between the two constitutes therein after annealing explains the considerable increase of the power conversion efficiency observed in these devices.
Item Type: | Articles |
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Additional Information: | Article |
Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Loos, Professor Joachim |
Authors: | Yang, X., Loos, J., Veenstra, S., Verhees, W., Wienk, M., Kroon, J., Michels, M., and Janssen, R. |
College/School: | College of Science and Engineering > School of Physics and Astronomy |
Journal Name: | Nano Letters |
Publisher: | American Chemical Society |
ISSN: | 1530-6984 |
ISSN (Online): | 1530-6992 |
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