Nanoscale morphology of high-performance polymer solar cells

Yang, X., Loos, J., Veenstra, S., Verhees, W., Wienk, M., Kroon, J., Michels, M. and Janssen, R. (2005) Nanoscale morphology of high-performance polymer solar cells. Nano Letters, 5(4), pp. 579-583. (doi: 10.1021/nl048120i)

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Abstract

Transmission electron microscopy and electron diffraction are used to study the changes in morphology of composite films of poly(3-hexylthiophene) (P3HT) and a methanofullerene derivative (PCBM) in bulk heterojunction solar cells. Thermal annealing produces and stabilizes a nanoscale interpenetrating network with crystalline order for both components. P3HT forms long, thin conducting nanowires in a rather homogeneous, nanocrystalline PCBM film. Both the improved crystalline nature of films and increased but controlled demixing between the two constitutes therein after annealing explains the considerable increase of the power conversion efficiency observed in these devices.

Item Type:Articles
Additional Information:Article
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Loos, Professor Joachim
Authors: Yang, X., Loos, J., Veenstra, S., Verhees, W., Wienk, M., Kroon, J., Michels, M., and Janssen, R.
College/School:College of Science and Engineering > School of Physics and Astronomy
Journal Name:Nano Letters
Publisher:American Chemical Society
ISSN:1530-6984
ISSN (Online):1530-6992

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