Assembly of modular asymmetric organic-inorganic polyoxometalate hybrids into anisotropic nanostructures

Rosnes, M.H., Musumeci, C., Pradeep, C.P., Mathieson, J.S., Long, D.L. , Song, Y.-F., Pignataro, B., Cogdell, R.J. and Cronin, L. (2010) Assembly of modular asymmetric organic-inorganic polyoxometalate hybrids into anisotropic nanostructures. Journal of the American Chemical Society, 132(44), pp. 15490-15492. (doi: 10.1021/ja1066338)

Abstract

Three organic-inorganic hybrid Mn-Anderson polyoxometalates (POMs), with both symmetrical and asymmetrical appended groups, have been synthesized, identified using electrospray mass spectrometry, and isolated using an approach that allows the three AA, BB, and AB compounds to be structurally characterized. Investigation of the self-assembly of the hybrids on hydrophilic surfaces reveals the formation of nanofibres with characteristics that reflect the nature of the substitution of the POM yielding a route to the programmed assembly of anisotropic hybrid nanostructures

• Item Type: Articles
• Status: Published
• Refereed: Yes
• Glasgow Author(s) Enlighten ID: Mathieson, Dr Jennifer and Song, Dr Yufei and Cogdell, Professor Richard and Long, Dr Deliang and Cronin, Professor Lee
• Authors: Rosnes, M.H., Musumeci, C., Pradeep, C.P., Mathieson, J.S., Long, D.L., Song, Y.-F., Pignataro, B., Cogdell, R.J., and Cronin, L.
• College/School: College of Medical Veterinary and Life Sciences > School of Molecular Biosciences
• Journal Name: Journal of the American Chemical Society
• ISSN: 0002-7863