Song, Y. -F., Long, D. L. , Kelly, S. E. and Cronin, L. (2008) Sorting the Assemblies of Unsymmetrically Covalently Functionalized Mn-Anderson Polyoxometalate Clusters with Mass Spectrometry. Inorganic Chemistry, 47(20), pp. 9137-9139. (doi: 10.1021/ic801366r)
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Abstract
The unsymmetrical Mn-Anderson polyoxometalate cluster, [N(C4H9)(4)](3)[MnMo6O18(C4H6O3NO2)(C4H6O3NH2)] (1; N(C4H9)(4)(+) = TBA(+)), has been prepared and characterized by X-ray crystallography and electrospray ionization mass spectrometry (ESI-MS). Covalent functionalization of compound 1 leads to the controlled assemblies of unsymmetrical alkoxopolyoxometalate clusters of compounds 2-5, which can be directly observed in solution as revealed by ESI-MS studies.
Item Type: | Articles |
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Keywords: | ASSEMBLIES BUILDING-BLOCKS CLUSTER CLUSTERS CRYSTALLOGRAPHY FUNCTIONALIZATION HETEROPOLYMOLYBDATES LIGANDS mass spectrometry MASS-SPECTROMETRY NANOSTRUCTURES organic-inorganic hybrids POLYOXOMETALATE POLYOXOMETALATE CLUSTERS POLYOXOMOLYBDATES STRUCTURAL CHARACTERIZATION X-RAY X-Ray Crystallography |
Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Song, Dr Yufei and Long, Dr Deliang and Cronin, Professor Lee |
Authors: | Song, Y. -F., Long, D. L., Kelly, S. E., and Cronin, L. |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | Inorganic Chemistry |
ISSN: | 0020-1669 |
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