Hybrid polyoxometalate clusters with appended aromatic platforms

Song, Y. -F., Long, D. L. and Cronin, L. (2010) Hybrid polyoxometalate clusters with appended aromatic platforms. CrystEngComm, 12(1), pp. 109-115. (doi: 10.1039/b910434h)

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The assembly of polyoxometalate architectures based on Mn-Anderson clusters capped with different aromatic platforms via the 'Tris' linker (Tris tris(hydroxymethyl) aminomethane), allows the formation and isolation of four new hybrid polyoxometalate clusters of 2-5 with the general composition of [n-N(C4H9)(4)](3)[MnMo6O18{(OCH2)(3)CN = CH-R}(2)]center dot solv., (R = (C6H5) 2, -(C6H5O) 3, -(C11H8N) 4 and -(C13H9) 5; solv. MeOH or H2O). These compounds were obtained simply by the reaction of compound 1, ([n-N(C4H9)(4)](3)[MnMo6O18{(OCH2)(3)CNH2}(2)]), with the corresponding aldehyde and the aromatic platforms were chosen to explore the design principles for covalently constructed POM aromatic-organic-inorganic hybrids.

Item Type:Articles
Glasgow Author(s) Enlighten ID:Song, Dr Yufei and Long, Dr Deliang and Cronin, Professor Lee
Authors: Song, Y. -F., Long, D. L., and Cronin, L.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:CrystEngComm

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