Ritchie, C.I., Streb, C., Thiel, J., Mitchell, S.G., Miras, H.N. , Long, D.L. , Boyd, T., Peacock, R.D., McGlone, T. and Cronin, L. (2008) Reversible redox reactions in an extended polyoxometalate framework solid. Angewandte Chemie (International Edition), 47(36), pp. 6881-6884. (doi: 10.1002/anie.200802594)
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Abstract
Back and forth: A concerted reversible redox reaction occurs in a pure metal oxide extended polyoxometalate framework when the accessible pockets are filled with a suitable redox agent. Direct control over the framework properties is demonstrated by repeated reversible switching between an expanded and a contracted structure. Successive recrystallizations from hot water repeatedly destroys and regenerates the framework.
Item Type: | Articles |
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Keywords: | cluster compounds CLUSTERS framework materials HYBRID LIGANDS METAL OXIDATION POLYOXOMETALATE polyoxometalates REDOX redox chemistry self-assembly TOPOLOGY. |
Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Peacock, Dr Robert and Moiras, Professor Haralampos and Long, Dr Deliang and Cronin, Professor Lee and Streb, Mr Carsten |
Authors: | Ritchie, C.I., Streb, C., Thiel, J., Mitchell, S.G., Miras, H.N., Long, D.L., Boyd, T., Peacock, R.D., McGlone, T., and Cronin, L. |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | Angewandte Chemie (International Edition) |
Journal Abbr.: | Angew. Chem. Int. Ed. Engl. |
ISSN: | 1433-7851 |
ISSN (Online): | 1521-3773 |
Published Online: | 31 July 2008 |
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