Ritchie, C., Li, F. Y., Pradeep, F. Y., Long, D. L. , Xu, L. and Cronin, L. (2009) A functional hybrid polyoxometalate framework based on a 'trilacunary' heteropolyanion [(P4W6O34)(2)Co2Na2(H2O)(2)](18-). Dalton Transactions(33), pp. 6483-6486. (doi: 10.1039/b907410d)
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Abstract
Using multifunctional organocations a novel heteropolyanion, [(P4W6O34)(2)Co2Na2(H2O)(2)](18-), with unprecedented structural features, has been observed, and extension of these clusters from molecules into 1D chains occurs through a dimeric cobalt species, with this material exhibiting reversible colour/magnetic susceptibility changes upon dehydration.
| Item Type: | Articles |
|---|---|
| Keywords: | BUILDING-BLOCKS CELTIC-RING ISOPOLYOXOTUNGSTATE CHEMISTRY CLUSTER CLUSTER CAGE CLUSTERS COMPLEXES FEATURES GROWTH HYBRID KEGGIN POLYOXOMETALATE MOLECULE MOLECULES POLYOXOMETALATE STRUCTURAL FEATURES |
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Long, Dr Deliang and Cronin, Professor Lee |
| Authors: | Ritchie, C., Li, F. Y., Pradeep, F. Y., Long, D. L., Xu, L., and Cronin, L. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Dalton Transactions |
| ISSN: | 1477-9226 |
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