Price, J. R., Clegg, J. K., Fenton, R. R., Lindoy, L. F., McMurtrie, J. C., Meehan, G. V., Parkin, A., Perkins, D. and Turner, P. (2009) Copper(I) Templated Synthesis of a 2,2 '-Bipyridine Derived 2-Catenane: Synthetic, Modelling, and X-ray Studies. Australian Journal of Chemistry, 62(9), pp. 1014-1019. (doi: 10.1071/CH09253)
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Abstract
Following molecular modelling employing molecular mechanics and semi-empirical (PM3) calculations as an aid to ligand design, a new copper(I)-containing [2]-catenane has been prepared by the reaction of 6,6'-bis[(4 ''-formylphenoxy) methyl]-2,2'-bipyridyl with 1,6-hexanediamine in the presence of a copper(I) template, followed by in situ sodium borohydride reduction of the tetra-imine species generated. The corresponding [2]-catenane was obtained as a deep orange crystalline solid. The X-ray structure of this product along with that of the corresponding bis-dialdehyde precursor copper(I) complex have been determined. In the latter case, the structure is pre-organized for catenane formation. The new catenane appears to be the first example of a tetrahedral metal template product incorporating a bis-bipyridyl derivative core. Isolation of the metal-free [2]-catenane has also been achieved following treatment of the copper(I) catenane complex in dimethylsulfoxide with tetrabutylammonium cyanide.
Item Type: | Articles |
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Keywords: | CATENANE COMPLEX COMPLEXES Copper(I) complex CORE DERIVATIVES DESIGN IN-SITU LIGAND MACROCYCLIC LIGANDS MOLECULAR MACHINE PROTOTYPES REDUCTION TEMPLATE TRANSITION-METAL-COMPLEXES X-RAY X-RAY-STRUCTURE |
Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Parkin, Dr Andrew |
Authors: | Price, J. R., Clegg, J. K., Fenton, R. R., Lindoy, L. F., McMurtrie, J. C., Meehan, G. V., Parkin, A., Perkins, D., and Turner, P. |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | Australian Journal of Chemistry |
ISSN: | 0004-9425 |
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