Pressure-induced Jahn-Teller switching in a Mn-12 nanomagnet

Parois, P., Moggach, S. A., Sanchez-Benitez, J., Kamenev, K. V., Lennie, A. R., Warren, J. E., Brechin, E. K., Parsons, S. and Murrie, M. (2010) Pressure-induced Jahn-Teller switching in a Mn-12 nanomagnet. Chemical Communications, 46(11), pp. 1881-1883. (doi: 10.1039/b923962f)

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Abstract

Pressure-induced switching of a fast-relaxing single-molecule magnet to a slow-relaxing isomer is observed for the first time by using a combination of high pressure single-crystal X-ray diffraction and high pressure magnetic measurements.

Item Type:Articles
Keywords:Anisotropy diffraction. high pressure, high-spin molecules, isomerism mn-12-acetate, neutron-scattering, single-molecule magnets, x-ray-diffraction.
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Murrie, Professor Mark
Authors: Parois, P., Moggach, S. A., Sanchez-Benitez, J., Kamenev, K. V., Lennie, A. R., Warren, J. E., Brechin, E. K., Parsons, S., and Murrie, M.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Chemical Communications
ISSN:1359-7345

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