Trading templates: Supramolecular transformations between {Co-13(II)} and {Co-12(II)} nanoclusters

Newton, G.N., Cooper, G.J.T. , Kogerler, P., Long, D.L. and Cronin, L. (2008) Trading templates: Supramolecular transformations between {Co-13(II)} and {Co-12(II)} nanoclusters. Journal of the American Chemical Society, 130(3), pp. 790-791. (doi: 10.1021/ja0768183)

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'Nuclearity switching' from a {Co-13} supercluster to a {Co-12} species via the addition of Co-3(2-) anions is reported and can be traced in solution using electrospray MS techniques. In addition, cryospray MS can be used to identify the entire cluster in solution despite the relative lability of its constituents.

Item Type:Articles
Glasgow Author(s) Enlighten ID:Long, Dr Deliang and Cooper, Dr Geoff and Cronin, Professor Lee
Authors: Newton, G.N., Cooper, G.J.T., Kogerler, P., Long, D.L., and Cronin, L.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Journal of the American Chemical Society

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Project CodeAward NoProject NamePrincipal InvestigatorFunder's NameFunder RefLead Dept
406941Realising the concept of the artificial chemical cell using vesiclesLeroy CroninEngineering & Physical Sciences Research Council (EPSRC)EP/D022304/1Chemistry