Mitchell, S. G., Ritchie, C., Long, D.L. and Cronin, L. (2008) Isolation of extendable transition metal incorporated polyoxometalate intermediates with structural control. Dalton Transactions(11), pp. 1415-1417. (doi: 10.1039/b715885h)
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Abstract
Three discrete cobalt-substituted silicotungstates, [Co-3(H2O)(B-beta-SiW9O34)(B-beta-SiW8O29(OH)(2))](12-) (1), [Co-3(H2O)(B-alpha-SiW9O34)(B-beta-SiW8O31)](14-) (2), and [Co9Cl2(OH)(3)(H2O)(9)(B-beta-SiW8O31)(3)](17-) (3), have been synthesized using a synthetic approach involving Co(II) ions, the dilacunary [gamma-SiW10O36](8-) polyanion and a bulky organic cation in basic media; all three compounds have been fully characterized and their position as structural intermediates in Co-containing silicotungstate chemistry is described.
Item Type: | Articles |
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Keywords: | ACHIEVEMENTS CATION CHEMISTRY CLUSTERS HETEROPOLYANIONS INTERMEDIATE ION IONS METAL POLYOXOMETALATE TRANSITION |
Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Long, Dr Deliang and Cronin, Professor Lee |
Authors: | Mitchell, S. G., Ritchie, C., Long, D.L., and Cronin, L. |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | Dalton Transactions |
ISSN: | 1477-9226 |
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