The trinity of polyoxometalates: connecting {M-12} Keggin and {M-18} Dawson clusters to triangles

Mitchell, S.G., Khanra, S., Miras, H.N. , Boyd, T., Long, D.L. and Cronin, L. (2009) The trinity of polyoxometalates: connecting {M-12} Keggin and {M-18} Dawson clusters to triangles. Chemical Communications(19), pp. 2712-2714. (doi: 10.1039/b903206a)

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Two topologically equivalent triangular POM aggregates based upon the Keggin (1) and Dawson (2) cluster species, with distinctive double {W-O-M} intra-molecular linkages involving Mn-III and Co-III ions are presented; both these compounds demonstrate electrocatalytic activity.

Item Type:Articles
Keywords:Cluster; clusters; coordination; Dawson; ion; isopolyoxotungstate; molecule; polyoxometalates polyoxotungstate
Glasgow Author(s) Enlighten ID:Moiras, Dr Haralampos and Khanra, Dr Sumit and Long, Dr Deliang and Cronin, Professor Lee
Authors: Mitchell, S.G., Khanra, S., Miras, H.N., Boyd, T., Long, D.L., and Cronin, L.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Chemical Communications
Journal Abbr.:Chem. Comm.
Publisher:Royal Society of Chemistry
ISSN (Online):1364-548X
Published Online:16 April 2009

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Project CodeAward NoProject NamePrincipal InvestigatorFunder's NameFunder RefLead Dept
400012Understanding and controlling the self assembly of nanoscale polyoxometalate clustersLeroy CroninEngineering & Physical Sciences Research Council (EPSRC)EP/C542827/1Chemistry