Miras, H.N. , Yan, J., Long, D.L. and Cronin, L. (2008) Structural evolution of "S"-shaped [H4W22O74](12-) and ""-shaped [H10W34O116](18-) isopolyoxotungstate clusters. Angewandte Chemie (International Edition), 47(44), pp. 8420-8423. (doi: 10.1002/anie.200802109)
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Abstract
Finding the missing species: Two isopolyoxotungstate clusters with unprecedented “S”-shaped [H<sub>4</sub>W<sub>22</sub>O<sub>74</sub>]<sup>12−</sup> and “§”-shaped [H<sub>10</sub>W<sub>34</sub>O<sub>116</sub>]<sup>18−</sup> geometries are presented. The development of this structural complexity comes from the structural evolution based on the {W<sub>11</sub>} fragment and establishes a new building block principle in isopolyoxotungstate chemistry. The evolved clusters can only be isolated in the presence of sulfite ions.
| Item Type: | Articles |
|---|---|
| Keywords: | CELTIC-RING ISOPOLYOXOTUNGSTATE CHEMISTRY CLUSTER cluster compounds CLUSTERS CROWN CRYSTAL-STRUCTURE EVOLUTION HF ISOPOLYOXOTUNGSTATE isopolyoxotungstates ISOPOLYTUNGSTATES MOLECULAR-STRUCTURE PARATUNGSTATE polyoxometalates POLYOXOTUNGSTATE Supramolecular Chemistry tungsten ZR. |
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Moiras, Professor Haralampos and Long, Dr Deliang and Cronin, Professor Lee |
| Authors: | Miras, H.N., Yan, J., Long, D.L., and Cronin, L. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Angewandte Chemie (International Edition) |
| Journal Abbr.: | Angew. Chem. Int. Ed. Engl. |
| Publisher: | Wiley - V C H Verlag GmbH & Co. KGaA |
| ISSN: | 1433-7851 |
| ISSN (Online): | 1521-3773 |
| Published Online: | 29 September 2008 |
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