Bridging the gap between solution and solid state studies in polyoxometalate chemistry: Discovery of a family of [V1M17]-based cages encapsulating two {(VO4)-O-V} moieties

Miras, H.N. , Long, D.L. , Kogerler, P. and Cronin, L. (2008) Bridging the gap between solution and solid state studies in polyoxometalate chemistry: Discovery of a family of [V1M17]-based cages encapsulating two {(VO4)-O-V} moieties. Dalton Transactions(2), pp. 214-221. (doi: 10.1039/b714285d)

Abstract

A family of polyoxometalates with the composition [H2V3M17O62](6-) features a Dawson-like architecture containing two tetrahedral {(VO4)-O-V} templates rather than main group hetero-anions ({PO4} or {SO4} etc.) typically associated with classical heteropolyacids, situated within a mixed-metal {(M17VO54)-V-VI-O-IV} cage and these clusters were first discovered using mass spectrometry.

• Item Type: Articles
• Keywords: BUILDING-BLOCKS CAGE CAGES CHEMISTRY CLUSTER CLUSTERS DAWSON ANIONS DISCOVERY DOT-S INTERACTIONS FAMILY FEATURES HETEROPOLYACIDS ISOMER mass spectrometry MASS-SPECTROMETRY ONE-ELECTRON OXIDATION POLYOXOMETALATE POLYOXOMETALATE CHEMISTRY polyoxometalates REDUCTION SOLID-STATE STATE SUBSTITUTED HETEROPOLYANIONS SYMMETRY TEMPLATE
• Status: Published
• Refereed: Yes
• Glasgow Author(s) Enlighten ID: Moiras, Professor Haralampos and Long, Dr Deliang and Cronin, Professor Lee
• Authors: Miras, H.N., Long, D.L., Kogerler, P., and Cronin, L.
• College/School: College of Science and Engineering > School of Chemistry
• Journal Name: Dalton Transactions
• Publisher: Royal Society of Chemistry
• ISSN: 1477-9226
• ISSN (Online): 1477-9234
• Published Online: 02 November 2007