Malkov, A.V., Czemerys, L. and Malyshev, D. A. (2009) Vanadium-Catalyzed Asymmetric Epoxidation of Allylic Alcohols in Water. Journal of Organic Chemistry, 74(9), pp. 3350-3355. (doi: 10.1021/jo900294h)
Full text not currently available from Enlighten.
Abstract
Asymmetric V-catalyzed epoxidation of allylic alcohols can be carried out in water with chiral ligands, which incorporate sulfonamide and hydroxamic acid fragments. Furthermore, the reaction, notorious for its ligand-deceleration effect, in water turned into the ligand-accelerated process. By using this aqueous protocol, a range of allylic alcohols were epoxidized with up to 94% ee.
| Item Type: | Articles |
|---|---|
| Keywords: | ACID ALCOHOLS ALKENES ALLYLIC ALCOHOLS AQUEOUS HYDROGEN-PEROXIDE Chiral CHIRAL HYDROXAMIC ACIDS COMPLEXES ENANTIOSELECTIVE EPOXIDATIONS LIGAND LIGANDS OXIDATIONS REACTIVITY TERT-BUTYL HYDROPEROXIDE UNFUNCTIONALIZED OLEFINS WATER |
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Malkov, Dr Andrei |
| Authors: | Malkov, A.V., Czemerys, L., and Malyshev, D. A. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Journal of Organic Chemistry |
| ISSN: | 0022-3263 |
University Staff: Request a correction | Enlighten Editors: Update this record
Altmetric
Altmetric