Imai, H., Akutagawa, T., Kudo, F., Ito, M., Toyoda, K., Noro, S., Cronin, L. and Nakamura, T. (2009) Structure, Magnetism, and Ionic Conductivity of the Gigantic {Mo-176}-Wheel Assembly: Na15Fe3Co16[Mo176O528H3(H2O)(80)]Cl-27 center dot 450H(2)O. Journal of the American Chemical Society, 131(38), 13578-+. (doi: 10.1021/ja9048042)
Full text not currently available from Enlighten.
Abstract
Single crystals of the nanoscale polyoxomolybdate wheel, Na15Fe3Co16[Mo176O528(H2O)(80)]Cl-27 center dot 450H(2)O, was synthesized by the condensation reaction of Na0.4Co0.8[MoO4]center dot 1.5H(2)O at low pH and in the presence of an iron-based reducing agent, and these crystals were characterized by the synchrotron-based X-ray single crystal analysis, magnetic susceptibility, and ionic conductivity measurements.
Item Type: | Articles |
---|---|
Keywords: | ASSEMBLIES CONDENSATION CONDUCTIVITY CRYSTAL PH SINGLE X-RAY |
Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Cronin, Professor Lee |
Authors: | Imai, H., Akutagawa, T., Kudo, F., Ito, M., Toyoda, K., Noro, S., Cronin, L., and Nakamura, T. |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | Journal of the American Chemical Society |
ISSN: | 0002-7863 |
University Staff: Request a correction | Enlighten Editors: Update this record