Hooper, T. N., Green, M., McGrady, J. E., Patel, J. R. and Russell, C. A. (2009) Synthesis and structural characterisation of stable cationic gold(I) alkene complexes. Chemical Communications(26), pp. 3877-3879. (doi: 10.1039/b908109g)
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Abstract
Treatment of [AuCl(PBu3t)] with AgSbF6 in CH2Cl2 at room temperature in the presence of the alkenes norbornene, norbornadiene, trans-cyclooctene, and also interestingly, isobutylene, leads to the formation of stable crystalline complexes [Au(PBu3t)(alkene)][SbF6], characterised by NMR spectroscopy and X-ray crystallography.
| Item Type: | Articles |
|---|---|
| Keywords: | ALKENES APPROXIMATION AU BEHAVIOR BOND CARBENE CATALYZED CYCLOISOMERIZATION COMPLEX COMPLEXES ENERGY ETHYLENE HYDROAMINATION MO NMR ROOM-TEMPERATURE SPECTROSCOPY TEMPERATURE X-RAY X-Ray Crystallography |
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | McGrady, Prof John |
| Authors: | Hooper, T. N., Green, M., McGrady, J. E., Patel, J. R., and Russell, C. A. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Chemical Communications |
| ISSN: | 1359-7345 |
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