Graham, K.F., Hindle, K.T., Jackson, S.D. , Williams, D.J.M. and Wuttke, S. (2010) Stereoselective synthesis of alicylic amines. Topics in Catalysis, 53(15-18), pp. 1121-1125. (doi: 10.1007/s11244-010-9544-2)
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Abstract
The hydrogenation 4-alkylanilines over Rh/silica catalysts display an antipathetic particle size effect suggesting that the active site is a terrace face. The effect of the solvent on product cis:trans ratio was related to polar solvents stabilising an imine intermediate. The products inhibited the reaction due to their increased basicity which allowed a strong metal-nitrogen interaction.
Item Type: | Articles |
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Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Jackson, Professor David |
Authors: | Graham, K.F., Hindle, K.T., Jackson, S.D., Williams, D.J.M., and Wuttke, S. |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | Topics in Catalysis |
ISSN: | 1022-5528 |
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