Access to new magnetic cores in Fe(III) and Fe(III)/Cu(II) spin clusters

Ferguson, A., McGregor, J., Brechin, E.K., Thomas, L.H. and Murrie, M. (2009) Access to new magnetic cores in Fe(III) and Fe(III)/Cu(II) spin clusters. Dalton Transactions(43), pp. 9395-9397. (doi: 10.1039/b913102g)

Abstract

The synthesis, structure and magnetic properties of [Fe14O4(OH)(4)(H2L)(2)(HL)(4)(piv)(20)] (1) and [Fe8Cu2O4(H2L)(4)-(HL)(2)(OBz)(12)] (2) are reported (H3L = 2-amino-2-(hydroxymethyl) propane-1,3-diol): both complexes have unique core structures and display non-zero spin ground states.

• Item Type: Articles
• Keywords: Bis-tris cluster, clusters, complex, complexes, core crystal-structure ,ground-state hysteresis, iron(iii), magnetic-properties, MN pivalate ,single-molecule-magnet, state symmetry.
• Status: Published
• Refereed: Yes
• Glasgow Author(s) Enlighten ID: Thomas, Dr Lynne and Murrie, Professor Mark
• Authors: Ferguson, A., McGregor, J., Brechin, E.K., Thomas, L.H., and Murrie, M.
• College/School: College of Science and Engineering > School of Chemistry
• Journal Name: Dalton Transactions
• ISSN: 1477-9226