Bis-Tris Propane as a New Polydentate Linker in the Synthesis of Iron(III) and Manganese(II/III) Complexes

Ferguson, A., Darwish, A., Graham, K., Schmidtmann, M., Parkin, A. and Murrie, M. (2008) Bis-Tris Propane as a New Polydentate Linker in the Synthesis of Iron(III) and Manganese(II/III) Complexes. Inorganic Chemistry, 47(21), pp. 9742-9744. (doi: 10.1021/ic8015386)

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Abstract

We describe the synthesis, structure, and magnetic properties of two new complexes, one decanuclear iron(III) cluster and one hexanuclear mixed-valence manganese(II/III) cluster, where the previously unexplored polydentate ligand Bis-tris propane {(CH2OH)(3)CNH(CH2)(3)NHC(CH2OH)(3)} is used to link small cluster fragments into high-nuclearity complexes.

Item Type:Articles
Keywords:Bis-tris cation, chemistry, cluster, clusters, complex, complexes, iron iron(iii), ligand, ligands, magnetic-properties, mixed-valence n,n,n',n'-tetrakis(2-hydroxyethyl),ethylenediamine, single-molecule magnet, structure.
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Schmidtmann, Mr Marc and Murrie, Professor Mark and Parkin, Dr Andrew
Authors: Ferguson, A., Darwish, A., Graham, K., Schmidtmann, M., Parkin, A., and Murrie, M.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:Inorganic Chemistry
ISSN:0020-1669

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