Cooke, G. , Daniels, L. M., Cazier, F., Garety, J. F., Hewage, S. G., Parkin, A., Rabani, G., Rotello, V. M., Wilson, C. C. and Woisel, P. (2007) The synthesis of a pyrrole-functionalized cyclobis( paraquat-p-phenylene) derivative and its corresponding [2]rotaxane and [2]catenane and their subsequent deposition onto an electrode surface. Tetrahedron, 63(45), pp. 11114-11121. (doi: 10.1016/j.tet.2007.08.027)
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Abstract
We report the convenient synthesis of a pyrrole-functionalized tetracationic cyclophane, [2]rotaxane, and [2]catenane. X-ray crystallography has confirmed the interlocked structure of the catenane. We have investigated the solution properties of these systems using solution electrochemistry, NMR, and UV-vis spectroscopy. We have also demonstrated that it is possible to immobilize these systems onto a platinum working electrode surface. We have shown that films of the cyclophane have the ability to undergo complexation with a di-alkyloxynaphthalene derivative. .
Item Type: | Articles |
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Keywords: | <2>CATENANE ACID CATENANE CRYSTAL-STRUCTURES CRYSTALLOGRAPHY ELECTROCHEMISTRY FILMS MOLECULAR MECCANO NMR ORDER OXIDATION PSEUDOPOLYROTAXANES SPECTROSCOPY Structure SURFACE SYSTEM SYSTEMS X-RAY X-Ray Crystallography |
Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Cooke, Professor Graeme and Wilson, Professor Charles and Rabani, Dr Gouher and Parkin, Dr Andrew |
Authors: | Cooke, G., Daniels, L. M., Cazier, F., Garety, J. F., Hewage, S. G., Parkin, A., Rabani, G., Rotello, V. M., Wilson, C. C., and Woisel, P. |
College/School: | College of Science and Engineering > School of Chemistry |
Journal Name: | Tetrahedron |
ISSN: | 0040-4020 |
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