Trapping, hysteresis and Ostwald ripening in hydrogen storage: a pore-scale imaging study

Goodarzi, S., Zhang, Y. , Foroughi, S., Bijeljic, B. and Blunt, M. J. (2024) Trapping, hysteresis and Ostwald ripening in hydrogen storage: a pore-scale imaging study. International Journal of Hydrogen Energy, 56, pp. 1139-1151. (doi: 10.1016/j.ijhydene.2023.12.029)

Abstract

Green hydrogen, produced from surplus electricity during peak production, can be injected into subsurface reservoirs and retrieved during high-demand periods. In this study, X-ray tomography was employed to examine hysteresis resulting from repeated hydrogen injection and withdrawal. An unsteady state experiment was performed to evaluate the distribution of hydrogen and brine after drainage and imbibition cycles: images of the pore-space configuration of fluids were taken immediately once injection had stopped and after waiting for a period of 16 h with no flow. A Bentheimer sandstone sample with a length of 60 mm and diameter of 12.8 mm was used, and hydrogen was injected at ambient temperature and a pore pressure of 1 MPa. The gas flow rate was decreased from 2 ml/min to 0.08 ml/min over three cycles of gas injection followed by water flooding, while the brine injection rate was kept constant. The results showed the presence of capillary pressure hysteresis and hydrogen migration through Ostwald ripening due to the diffusion of gas dissolved in the brine. These phenomena were characterized through analysis of interfacial curvature, area, connectivity and pore occupancy. The hydrogen tended to reside in the larger pore spaces, consistent with water-wet conditions. 16 h after flow had stopped, the hydrogen aggregated into larger ganglia with a single large connected ganglion dominating the volume. Moreover, the Euler characteristic decreased after 16 h, indicating an improvement in connectivity. The work implies that Ostwald ripening – mass transport of dissolved gas – leads to less hysteresis and better connectivity than would be assumed ignoring this effect, as done in assessments of hydrocarbon flow and trapping.

• Item Type: Articles
• Additional Information: We thank Shell through the Digital Rocks program and EPSRC, United Kingdom grant number EP/V038044/1 INFUSE: Interface with the Future - Underpinning Science to Support the Energy Transition for funding this work.
• Status: Published
• Refereed: Yes
• Glasgow Author(s) Enlighten ID: Zhang, Dr Yihuai
• Authors: Goodarzi, S., Zhang, Y., Foroughi, S., Bijeljic, B., and Blunt, M. J.
• College/School: College of Science and Engineering > School of Engineering > Systems Power and Energy
• Journal Name: International Journal of Hydrogen Energy
• Publisher: Elsevier
• ISSN: 0360-3199
• Published Online: 03 January 2024
• Copyright Holders: Copyright © 2023 The Authors
• First Published: First published in International Journal of Hydrogen Energy 56:1139-1151
• Publisher Policy: Reproduced under a Creative Commons licence