Manganese oxoborate‐based nanostructures as novel oxygen evolution catalysts in neutral media

Elmaci, G., Icten, O., Ozer, D., Ozgenc, G., Ertekin, Z. , Ali Kose, D., Pekmez, K. and Zumreoglu‐Karan, B. (2021) Manganese oxoborate‐based nanostructures as novel oxygen evolution catalysts in neutral media. ChemNanoMat, 7(12), pp. 1340-1347. (doi: 10.1002/cnma.202100256)

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Abstract

The development of electrocatalysts for the OER (oxygen evolution reaction) process is an ongoing challenge in producing sustainable energy systems. Herein, we report QS (quasi-spherical), IR (irregular), and NR (nanorod) Mn2OBO3 (manganese oxoborate), modified with a carbon support, as candidate electrocatalysts for OER in a neutral medium. QS-, IR- and NR-Mn2OBO3 catalysts displayed low onset potentials of 201 mV, 205 mV, and 208 mV and Tafel slope results of 94 mV dec−1, 97 mV dec−1, and 106 mV dec−1, respectively. As a result of the long-term stability tests, it was determined that the NR-Mn2OBO3 sample was extremely stable compared to the QS- and IR-catalysts. This work introduces a new Mn2OBO3/C composite catalyst that displays efficient OER performance at a neutral medium and provides a different perspective for catalyst development strategies.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Ertekin, Dr Zeliha
Authors: Elmaci, G., Icten, O., Ozer, D., Ozgenc, G., Ertekin, Z., Ali Kose, D., Pekmez, K., and Zumreoglu‐Karan, B.
College/School:College of Science and Engineering > School of Chemistry
Journal Name:ChemNanoMat
Publisher:Wiley
ISSN:2199-692X
ISSN (Online):2199-692X
Published Online:22 September 2021

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