Colour of the past in South Caucasus: The first archaeometric investigation on rock art and pigment residues from Georgia

Batiashvili, M., Gallinaro, M., Balossi Restelli, F., Medeghini, L., Young, C. and Botticelli, M. (2023) Colour of the past in South Caucasus: The first archaeometric investigation on rock art and pigment residues from Georgia. Quaternary International, 658, pp. 1-13. (doi: 10.1016/j.quaint.2023.03.019)

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Abstract

This research is the first archaeometric investigation of Damirgaya and Trialeti painted rock art and pigments from grinding tools from the Neolithic settlement of Khramis Didi Gora, in South Caucasus, Georgia. The aims of this research are to characterise the rocks and pigments including identification of organic binder, as well as investigate the compatibility of inorganic pigments with locally available supplies and methods of production. Stylistic similarities and influences are compared with adjacent archaeological sites from Armenia and Azerbaijan, where traces of monochromatic red pigment were recovered in settlements, barrows and artefacts. Optical microscopy (OM) on loose samples and thin sections, X-ray powder diffraction (XRPD), and scanning electron microscopy with energy dispersive spectroscopy (SEM-EDS) were used to determine the mineralogical and chemical composition of the samples. Employing micro-Fourier-transform infrared (μ-FTIR) and Raman spectroscopy, compounds were further characterized in both rock paintings and grinding tools. It was not possible to identify or ascertain the presence of binders, either because of their low concentration or complete molecular breakdown deterioration. From the pigment residues on both the rock art and grinding tools, hematite was the main colouring agent, with different associated minerals. For the rock samples, it was found that the rock art at Trialeti is on a dacite, whereas the one from Damirgaya is on a rock composed of quartz, with traces of iron oxides and phyllosilicates, suggesting that the rock originated from hydrothermal activity. The research presented here is the first chemical and mineralogical characterization of pigment residues and rock art from South Caucasian prehistory.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Botticelli, Dr Michela and Young, Professor Christina
Authors: Batiashvili, M., Gallinaro, M., Balossi Restelli, F., Medeghini, L., Young, C., and Botticelli, M.
College/School:College of Arts & Humanities > School of Culture and Creative Arts
College of Arts & Humanities > School of Culture and Creative Arts > History of Art
Journal Name:Quaternary International
Publisher:Elsevier
ISSN:1040-6182
ISSN (Online):1873-4553
Published Online:22 April 2023
Copyright Holders:Copyright © 2023 The Authors
First Published:First published in Quaternary International Volume 658:1-13
Publisher Policy:Reproduced under a Creative Commons License

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Project CodeAward NoProject NamePrincipal InvestigatorFunder's NameFunder RefLead Dept
300866PISTACHIO: Photonic Imaging Strategies for Technical Art Conservation and HistoryChristina YoungEngineering and Physical Sciences Research Council (EPSRC)EP/R033013/1Arts - History of Art