Martin, M. L., Wilson, C. and Boyer, A. (2023) Stereodefined synthesis of cyclic amidines by domino 1,7-H shift and 6π electrocyclisation. Chemical Communications, 59(33), pp. 4899-4902. (doi: 10.1039/D3CC01127E) (PMID:37013852)
![[img]](https://eprints.gla.ac.uk/style/images/fileicons/text.png) |
Text
295805.pdf - Published Version Available under License Creative Commons Attribution Non-commercial. 809kB |
Abstract
Unsaturated N2-sulfonyl amidines are transformed into valuable N-heterocyclic products when heated with BF2OTf. Mechanism studies suggest a domino 1,7-H shift, activating a C–H bond, followed by electrocylisation that results in stereodefined cyclic amidines.
| Item Type: | Articles |
|---|---|
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Wilson, Dr Claire and Boyer, Dr Alistair and Martin, Mr Matthew |
| Authors: | Martin, M. L., Wilson, C., and Boyer, A. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Chemical Communications |
| Publisher: | Royal Society of Chemistry |
| ISSN: | 1359-7345 |
| ISSN (Online): | 1364-548X |
| Published Online: | 04 April 2023 |
| Copyright Holders: | Copyright © 2023 The Royal Society of Chemistry |
| First Published: | First published in Chemical Communications 59:4899-4902 |
| Publisher Policy: | Reproduced under a Creative Commons License |
University Staff: Request a correction | Enlighten Editors: Update this record
Deposit and Record Details
Deposit and Record Details