Phase structure and electrical properties of K0.5Na0.5(Nb0.94Sb0.06) O-3-LiTaO3 lead-free piezoelectric ceramics

Lin, D., Kwok, K.W., Lam, K.H. and Chan, H.L.W. (2008) Phase structure and electrical properties of K0.5Na0.5(Nb0.94Sb0.06) O-3-LiTaO3 lead-free piezoelectric ceramics. Journal of Physics D: Applied Physics, 41(5), 052002. (doi: 10.1088/0022-3727/41/5/052002)

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Abstract

Lead-free piezoelectric ceramics (1-x)K0.5Na0.5(Nb0.94Sb0.06)O3–xLiTaO3 have been fabricated by a conventional solid-state sintering technique. The ceramics can be well sintered at 1080–1110 °C and exhibit a dense, single-phase perovskite structure at x ≤ 0.06. Coexistence of the tetragonal and orthorhombic phases is formed in the ceramics with 0.02 < x < 0.05, leading to a significant enhancement in piezoelectric properties. For the ceramic with x = 0.04, the piezoelectric properties become optimum: piezoelectric constant d33 = 271 pC N−1, electromechanical coupling coefficients kP = 0.53 and kt = 0.43. Moreover, the ceramics are non-deliquescent and exhibit excellent performance in transducer applications, indicating that the ceramics are ready for replacing lead-containing ceramics in practical applications.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Lam, Dr Koko
Authors: Lin, D., Kwok, K.W., Lam, K.H., and Chan, H.L.W.
College/School:College of Science and Engineering > School of Engineering > Systems Power and Energy
Journal Name:Journal of Physics D: Applied Physics
Publisher:IOP Publishing
ISSN:0022-3727
ISSN (Online):1361-6463

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