Shi, L., Li, Y., Zeng, F., Ran, S., Dong, C., Leu, S.-Y., Boles, S. T. and Lam, K. H. (2019) In situ growth of amorphous Fe2O3 on 3D interconnected nitrogen-doped carbon nanofibers as high-performance anode materials for sodium-ion batteries. Chemical Engineering Journal, 356, pp. 107-116. (doi: 10.1016/j.cej.2018.09.018)
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Abstract
In this work, a novel porous amorphous Fe2O3/nitrogen-doped carbon composite as a promising anode material for sodium-ion batteries has been fabricated by in situ growing amorphous Fe2O3 on 3D interconnected nitrogen-doped carbon nanofibers. The as-prepared composite exhibits superior sodium storage properties. It delivers a high reversible capacity of 408 mA h g−1 after 350 cycles at a current density of 100 mA g−1 and a good rate capability of 183 mA h g−1 at 3 A g−1. The excellent electrochemical performance is owing to the synergistic effects of the amorphous structure of Fe2O3 and the 3D interconnected nitrogen-doped carbon network with high nitrogen doping content (10 atom%), which do not only relieve the internal stress of the electrode and accommodate more electrochemical active sites for Na+ storage, but also buffer the volume changes of amorphous Fe2O3 as well as facilitate the electronic and ionic transportation during cycling.
Item Type: | Articles |
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Status: | Published |
Refereed: | Yes |
Glasgow Author(s) Enlighten ID: | Lam, Dr Koko |
Authors: | Shi, L., Li, Y., Zeng, F., Ran, S., Dong, C., Leu, S.-Y., Boles, S. T., and Lam, K. H. |
College/School: | College of Science and Engineering > School of Engineering > Systems Power and Energy |
Journal Name: | Chemical Engineering Journal |
Publisher: | Elsevier |
ISSN: | 1385-8947 |
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