Conducting polymer based visible light photocatalytic composites for pollutant removal: progress and prospects

Saianand, G., Gopalan, A.-I., Wan, L., Venkatramanan, K., Roy, V. A.L. , Sonar, P., Lee, D.-E. and Naidu, R. (2022) Conducting polymer based visible light photocatalytic composites for pollutant removal: progress and prospects. Environmental Technology and Innovation, 28, 102698. (doi: 10.1016/j.eti.2022.102698)

Abstract

Conducting polymers (CPs) have been proved to be instrumental in enhancing photocatalytic efficacy owing to their unique physicochemical properties and energy levels. In this regard, titanium dioxide (TiO2) has been investigated in transdisciplinary research areas (like catalysis, energy technologies, health, and environment) due to its desirable characteristics. In the process of developing advanced photocatalysts, novel inorganic–organic heterojunction design based materials have been explored and developed in contrast to conventional, inorganic–inorganic type semiconducting photocatalysts (SCPs). In this context, hybrid/composite SCPs comprising CPs and TiO2, have received significant attention for enhancing photocatalytic efficacy in terms of activity as well as visible light activation. The synergistic contribution from CPs (here we focus only on polyaniline (PANI) and polypyrrole (PPy)) and TiO2 have been proved to enhance light-absorption capability in the visible region, photogenerated extraction, and higher stability. Importantly, the published literature (before 2015) on the photocatalysis of TiO2-CP composites mainly discusses in terms of the sensitizing aspects of CP for TiO2. However, there is a critical need to review the literature (beyond 2015) to explore the state of art progress concerning the mechanism of photocatalytic performances as phenomenal parallel developments and knowledge gaps have been addressed on new kinds of heterojunction formation (like S-Scheme over traditional ones), band tuning and interfacial contact effects between two SCPs. In particular, this topical review aims to capture and highlight the current advancements (2016–2021) in relevance to the visible light photocatalytic performance of CP–TiO2 functional composites, which include nanostructures and multi-components. The predominantly available literature over the last five years on the application of CPs–TiO2 functional composites for monitoring or removal of pollutants under visible light activation is reviewed giving importance to revealing the role of CP in concurrent enhancement in both visible light activation and photocatalytic performances. Finally, we elaborate on the challenges and future outlook for advanced research and development in this area.

• Item Type: Articles
• Additional Information: The authors (G.S and R.N) appreciate the funding support from Cooperative Research Centre for Contamination Assessment and Remediation of the Environment (CRC CARE) to carry out this literature review. This work was also supported by the National Research Foundation of Korea (NRF) grant funded by the Korean government (MSIT) (No. NRF-2019R1A2C3003890).
• Status: Published
• Refereed: Yes
• Glasgow Author(s) Enlighten ID: Vellaisamy, Professor Roy
• Authors: Saianand, G., Gopalan, A.-I., Wan, L., Venkatramanan, K., Roy, V. A.L., Sonar, P., Lee, D.-E., and Naidu, R.
• College/School: College of Science and Engineering > School of Engineering > Electronics and Nanoscale Engineering
• Journal Name: Environmental Technology and Innovation
• Publisher: Elsevier
• ISSN: 2352-1864
• ISSN (Online): 2352-1864
• Published Online: 02 June 2022
• Copyright Holders: Copyright © 2022 The Author(s)
• First Published: First published in Environmental Technology and Innovation 28: 102698
• Publisher Policy: Reproduced under a Creative Commons licence