A passive sampling method for radiocarbon analysis of soil respiration using molecular sieve

Garnett, M.H., Hartley, I.P., Hopkins, D.W., Sommerkorn, M. and Wookey, P.A. (2009) A passive sampling method for radiocarbon analysis of soil respiration using molecular sieve. Soil Biology and Biochemistry, 41(7), pp. 1450-1456. (doi: 10.1016/j.soilbio.2009.03.024)

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Abstract

Radiocarbon analysis of soil CO2 can provide information on the age, source and turnover rate of soil organic C. We developed a new method for passively trapping respired CO2 on molecular sieve, allowing it to be returned to the laboratory and recovered for C isotope analysis. We tested the method on a soil at a grassland site, and using a synthetic soil created to provide a contrasting isotopic signature. As with other passive sampling techniques, a small amount of fractionation of the 13C isotope occurs during sampling, which we have quantified, otherwise the results show that the molecular sieve traps a sufficiently large and representative sample of CO2 for C isotope analysis. Since 14C results are routinely corrected for mass-dependent fractionation, our results show that passive sampling of soil respiration using molecular sieve offers a reliable method to collect soil-respired CO2 for 14C analysis.

Item Type:Articles
Keywords:Soil respiration, CO2, radiocarbon, molecular sieve
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Garnett, Dr Mark
Authors: Garnett, M.H., Hartley, I.P., Hopkins, D.W., Sommerkorn, M., and Wookey, P.A.
Subjects:G Geography. Anthropology. Recreation > GE Environmental Sciences
Q Science > QH Natural history > QH345 Biochemistry
College/School:College of Science and Engineering > Scottish Universities Environmental Research Centre
Journal Name:Soil Biology and Biochemistry
Journal Abbr.:Soil biol. biochem.
Publisher:Elsevier
ISSN:0038-0717
ISSN (Online):1879-3428
Published Online:16 April 2009
Copyright Holders:Copyright © 2009 Elsevier
First Published:First published in Soil Biology and Biochemistry 41(7):1450-1456
Publisher Policy:Reproduced in accordance with the copyright policy of the publisher

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