Localization length scales of triplet excitons in singlet fission materials

Bayliss, S. L. , Thorley, K. J., Anthony, J. E., Bouchiat, H., Greenham, N. C. and Chepelianskii, A. D. (2015) Localization length scales of triplet excitons in singlet fission materials. Physical Review B, 92(11), 115432. (doi: 10.1103/PhysRevB.92.115432)

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Abstract

We measure the dielectric confinement length scales of triplet excitons in organic semiconductors by jointly measuring their microwave-domain electric and magnetic susceptibilities. We apply this technique to characterize triplet excitons in two singlet fission materials with distinct solid-state packing and correlate the extracted localization length scales with the role of the excitonic environment. By using the magnetic susceptibility simultaneously determined through our experiments, we compare the independently extracted dielectric and spin-spin localization length scales, highlighting the role of local anisotropy on the properties of excitonic triplet states.

Item Type:Articles
Status:Published
Refereed:Yes
Glasgow Author(s) Enlighten ID:Bayliss, Dr Sam
Authors: Bayliss, S. L., Thorley, K. J., Anthony, J. E., Bouchiat, H., Greenham, N. C., and Chepelianskii, A. D.
College/School:College of Science and Engineering > School of Engineering > Electronics and Nanoscale Engineering
Journal Name:Physical Review B
Publisher:American Physical Society
ISSN:1098-0121
ISSN (Online):1550-235X
Published Online:21 September 2015

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