Synthesis of H_xLi_1-xLaTiO₄ from quantitative solid-state reactions at room temperature

Yip, T.W.S., Cussen, E.J. and MacLaren, D.A. (2010) Synthesis of H_xLi_1-xLaTiO₄ from quantitative solid-state reactions at room temperature. Chemical Communications, 46(5), pp. 698-700. (doi: 10.1039/b920837b)

Abstract

The layered perovskite HLaTiO4 reacts stoichiometrically with LiOH·H₂O at room temperature to give targeted compositions in the series H_xLi_1-xLaTiO₄. Remarkably, the Li⁺ and H⁺ ions are quantitatively exchanged in the solid state and this allows stoichiometric control of ion exchange for the first time in this important series of compounds.

• Item Type: Articles
• Status: Published
• Refereed: Yes
• Glasgow Author(s) Enlighten ID: MacLaren, Professor Donald
• Authors: Yip, T.W.S., Cussen, E.J., and MacLaren, D.A.
• Subjects: Q Science > QD Chemistry
• College/School: College of Science and Engineering > School of Physics and Astronomy
• Journal Name: Chemical Communications
• Journal Abbr.: Chem. Comm.
• Publisher: Royal Society of Chemistry
• ISSN: 1359-7345
• ISSN (Online): 1364-548X
• Published Online: 30 November 2009
• Copyright Holders: Copyright © 2010 Royal Society of Chemistry
• First Published: First published in Chemical Communications 46(5):698-700
• Publisher Policy: Reproduced in accordance with the copyright policy of the publisher.