Guégano, X. et al. (2008) Pronounced electrochemical amphotericity of a fused donor-acceptor compound: a planar merge of TTF with a TCNQ-type bithienoquinoxaline. Chemistry: A European Journal, 15(1), pp. 63-66. (doi: 10.1002/chem.200802011)
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Abstract
Narrowing the gap: A compactly fused π‐conjugated molecule combines a high‐lying HOMO with a low‐lying LUMO (Eox−Ered=0.52 eV) and a fairly low‐lying LUMO+1 on the bridging unit, giving rise to strong optical charge‐transfer transitions. A facile electron transfer has been observed by EPR and NMR spectroscopies.
| Item Type: | Articles |
|---|---|
| Status: | Published |
| Refereed: | Yes |
| Glasgow Author(s) Enlighten ID: | Skabara, Professor Peter |
| Authors: | Guégano, X., Kanibolotsky, A. L., Blum, C., Mertens, S. F. L., Liu, S.-X., Neels, A., Hagemann, H., Skabara, P. J., Leutwyler, S., Wandlowski, T., Hauser, A., and Decurtins, S. |
| College/School: | College of Science and Engineering > School of Chemistry |
| Journal Name: | Chemistry: A European Journal |
| Publisher: | Wiley |
| ISSN: | 0947-6539 |
| ISSN (Online): | 1521-3765 |
| Published Online: | 03 December 2008 |
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